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Diversity-oriented synthesis of P-stereogenic and axially chiral monodentate biaryl phosphines enabled by C-P bond cleavage

Chiral monodentate biaryl phosphines (MOPs) have attracted intense attention as chiral ligands over the past decades. However, the creation of structurally diverse chiral MOPs with both P- and axial chirality is still in high demand but challenging. Here, we show a distinct strategy for diversity-or...

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Detalles Bibliográficos
Autores principales: Pang, Liangzhi, Huang, Zhan, Sun, Qilin, Li, Gen, Liu, Jiaojiao, Li, Baoli, Ma, Congyue, Guo, Jiaxu, Yao, Chuanzhi, Yu, Jie, Li, Qiankun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10363526/
https://www.ncbi.nlm.nih.gov/pubmed/37482556
http://dx.doi.org/10.1038/s41467-023-40138-8