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The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins
This review covers palladium-catalyzed typical Mizoroki–Heck cross-coupling reactions of aryl halides with in situ generated alkenes, by following a typical Heck coupling mechanism to form substituted olefins unlike direct cross-coupling of alkenes with aryl halides in Heck olefination. These reacti...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10367967/ https://www.ncbi.nlm.nih.gov/pubmed/37497097 http://dx.doi.org/10.1039/d3ra03533f |
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author | Koranne, Anushka Turakhia, Shrishty Jha, Vikesh Kumar Gupta, Sangeeta Ravi, Rangnath Mishra, Abhijeet Aggarwal, Anil K. Jha, Chandan Kumar Dheer, Neelu Jha, Abadh Kishor |
author_facet | Koranne, Anushka Turakhia, Shrishty Jha, Vikesh Kumar Gupta, Sangeeta Ravi, Rangnath Mishra, Abhijeet Aggarwal, Anil K. Jha, Chandan Kumar Dheer, Neelu Jha, Abadh Kishor |
author_sort | Koranne, Anushka |
collection | PubMed |
description | This review covers palladium-catalyzed typical Mizoroki–Heck cross-coupling reactions of aryl halides with in situ generated alkenes, by following a typical Heck coupling mechanism to form substituted olefins unlike direct cross-coupling of alkenes with aryl halides in Heck olefination. These reactions solve the issue of alkenes undergoing polymerization at high temperatures and increase reaction efficiency by reducing the reaction time and purification steps. |
format | Online Article Text |
id | pubmed-10367967 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-103679672023-07-26 The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins Koranne, Anushka Turakhia, Shrishty Jha, Vikesh Kumar Gupta, Sangeeta Ravi, Rangnath Mishra, Abhijeet Aggarwal, Anil K. Jha, Chandan Kumar Dheer, Neelu Jha, Abadh Kishor RSC Adv Chemistry This review covers palladium-catalyzed typical Mizoroki–Heck cross-coupling reactions of aryl halides with in situ generated alkenes, by following a typical Heck coupling mechanism to form substituted olefins unlike direct cross-coupling of alkenes with aryl halides in Heck olefination. These reactions solve the issue of alkenes undergoing polymerization at high temperatures and increase reaction efficiency by reducing the reaction time and purification steps. The Royal Society of Chemistry 2023-07-25 /pmc/articles/PMC10367967/ /pubmed/37497097 http://dx.doi.org/10.1039/d3ra03533f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Koranne, Anushka Turakhia, Shrishty Jha, Vikesh Kumar Gupta, Sangeeta Ravi, Rangnath Mishra, Abhijeet Aggarwal, Anil K. Jha, Chandan Kumar Dheer, Neelu Jha, Abadh Kishor The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins |
title | The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins |
title_full | The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins |
title_fullStr | The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins |
title_full_unstemmed | The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins |
title_short | The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins |
title_sort | mizoroki–heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10367967/ https://www.ncbi.nlm.nih.gov/pubmed/37497097 http://dx.doi.org/10.1039/d3ra03533f |
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