Synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) as a catalyst

The anomeric effect highlights the significant influence of the functional group and reaction conditions on oxidation–reduction. This article successfully investigates the anomeric effect in the synthesis of picolinate and picolinic acid derivatives through a multi-component reaction involving 2-oxo...

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Autores principales: Babaee, Saeed, Sepehrmansourie, Hassan, Zarei, Mahmoud, Zolfigol, Mohammad Ali, Hosseinifard, Mojtaba
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10368083/
https://www.ncbi.nlm.nih.gov/pubmed/37497088
http://dx.doi.org/10.1039/d3ra03438k
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author Babaee, Saeed
Sepehrmansourie, Hassan
Zarei, Mahmoud
Zolfigol, Mohammad Ali
Hosseinifard, Mojtaba
author_facet Babaee, Saeed
Sepehrmansourie, Hassan
Zarei, Mahmoud
Zolfigol, Mohammad Ali
Hosseinifard, Mojtaba
author_sort Babaee, Saeed
collection PubMed
description The anomeric effect highlights the significant influence of the functional group and reaction conditions on oxidation–reduction. This article successfully investigates the anomeric effect in the synthesis of picolinate and picolinic acid derivatives through a multi-component reaction involving 2-oxopropanoic acid or ethyl 2-oxopropanoate, ammonium acetate, malononitrile, and various aldehydes. To facilitate this process, we employed UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) as a novel nanoporous heterogeneous catalyst. The inclusion of phosphorous acid tags on the UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) offers the potential for synthesizing picolinates at ambient temperature.
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spelling pubmed-103680832023-07-26 Synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) as a catalyst Babaee, Saeed Sepehrmansourie, Hassan Zarei, Mahmoud Zolfigol, Mohammad Ali Hosseinifard, Mojtaba RSC Adv Chemistry The anomeric effect highlights the significant influence of the functional group and reaction conditions on oxidation–reduction. This article successfully investigates the anomeric effect in the synthesis of picolinate and picolinic acid derivatives through a multi-component reaction involving 2-oxopropanoic acid or ethyl 2-oxopropanoate, ammonium acetate, malononitrile, and various aldehydes. To facilitate this process, we employed UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) as a novel nanoporous heterogeneous catalyst. The inclusion of phosphorous acid tags on the UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) offers the potential for synthesizing picolinates at ambient temperature. The Royal Society of Chemistry 2023-07-25 /pmc/articles/PMC10368083/ /pubmed/37497088 http://dx.doi.org/10.1039/d3ra03438k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Babaee, Saeed
Sepehrmansourie, Hassan
Zarei, Mahmoud
Zolfigol, Mohammad Ali
Hosseinifard, Mojtaba
Synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) as a catalyst
title Synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) as a catalyst
title_full Synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) as a catalyst
title_fullStr Synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) as a catalyst
title_full_unstemmed Synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) as a catalyst
title_short Synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using UiO-66(Zr)-N(CH(2)PO(3)H(2))(2) as a catalyst
title_sort synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using uio-66(zr)-n(ch(2)po(3)h(2))(2) as a catalyst
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10368083/
https://www.ncbi.nlm.nih.gov/pubmed/37497088
http://dx.doi.org/10.1039/d3ra03438k
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