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Optical Resolution of Carboxylic Acid Derivatives of Homoleptic Cyclometalated Iridium(III) Complexes via Diastereomers Formed with Chiral Auxiliaries

[Image: see text] We report on a facile method for the optical resolution of cyclometalated iridium(III) (Ir(III)) complexes via diastereomers formed with chiral auxiliaries. The racemic carboxylic acids of Ir(III) complexes (fac-4 (fac-Ir(ppyCO(2)H)(3) (ppy: 2-phenylpyridine)), fac-6 (fac-Ir(tpyCO(...

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Detalles Bibliográficos
Autores principales:	Kanbe, Azusa, Yokoi, Kenta, Yamada, Yasuyuki, Tsurui, Makoto, Kitagawa, Yuichi, Hasegawa, Yasuchika, Ogata, Daiji, Yuasa, Junpei, Aoki, Shin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10369494/ https://www.ncbi.nlm.nih.gov/pubmed/37432912 http://dx.doi.org/10.1021/acs.inorgchem.3c00685

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