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Understanding Precatalyst Activation and Speciation in Manganese-Catalyzed C–H Bond Functionalization Reactions

[Image: see text] An investigation into species formed following precatalyst activation in Mn-catalyzed C–H bond functionalization reactions is reported. Time-resolved infrared spectroscopy demonstrates that light-induced CO dissociation from precatalysts [Mn(C^N)(CO)(4)] (C^N = cyclometalated 2-phe...

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Detalles Bibliográficos
Autores principales:	Eastwood, Jonathan B., Hammarback, L. Anders, Burden, Thomas J., Clark, Ian P., Towrie, Michael, Robinson, Alan, Fairlamb, Ian J. S., Lynam, Jason M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10369674/ https://www.ncbi.nlm.nih.gov/pubmed/37502314 http://dx.doi.org/10.1021/acs.organomet.3c00004

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