Enhancement of oxygen sensing performance of metalloporphyrin film modified with nano Al(2)O(3) powder

In this work, the metalloporphyrin film of PtOEP/Poly (St-co-TFEMA) modified by nano Al(2)O(3) powder was prepared, and the enhancement performance of oxygen sensing was studied in detail. It was verified that the modified film extended the residence time of oxygen through the characterization of SEM. The phosphorescence intensity changes with the content of Al(2)O(3) and PtOEP were studied. The Stern-Volmer equations before and after modification of Al(2)O(3) powder was compared. It was found that the linearity of the calibration curve was still high, but the oxygen sensitivity value of K(SV) was significantly improved due to the increase of quenching probability between indicator and oxygen. Finally, the stability test shows that the Al(2)O(3)@PtOEP/Poly (St-co-TFEMA) oxygen sensing film presents a strong anti-photo-bleaching ability, and the response time is shortened.