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Biochar Derived from Pineapple Leaf Non-Fibrous Materials and Its Adsorption Capability for Pesticides
[Image: see text] Non-fibrous materials (NFMs) are typically discarded during pineapple leaf fiber processing. The underutilized NFM waste was proposed for use in this work as a raw material for the production of biochar . The removal of pesticides (acetamiprid, imidacloprid, or methomyl) from water...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10373191/ https://www.ncbi.nlm.nih.gov/pubmed/37521671 http://dx.doi.org/10.1021/acsomega.3c02328 |
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author | Srikhaow, Assadawoot Win, Ei Ei Amornsakchai, Taweechai Kiatsiriroat, Tanongkiat Kajitvichyanukul, Puangrat Smith, Siwaporn M. |
author_facet | Srikhaow, Assadawoot Win, Ei Ei Amornsakchai, Taweechai Kiatsiriroat, Tanongkiat Kajitvichyanukul, Puangrat Smith, Siwaporn M. |
author_sort | Srikhaow, Assadawoot |
collection | PubMed |
description | [Image: see text] Non-fibrous materials (NFMs) are typically discarded during pineapple leaf fiber processing. The underutilized NFM waste was proposed for use in this work as a raw material for the production of biochar . The removal of pesticides (acetamiprid, imidacloprid, or methomyl) from water was then investigated using the NFM derived biochar (NFMBC). The pseudo-second-order kinetic data suggested chemisorption of pesticide on NFMBC. While acetamiprid or imidacloprid adsorption on NFMBC occurred primarily via multi-layered adsorption (best fitted with the Freundlich isotherms), the Sips adsorption isotherms matched with the experimental data, implying heterogeneous adsorption of methomyl on the biochar surface. The adsorption capacities for acetamiprid, methomyl, and imidacloprid are 82.18, 36.16, and 28.98 mg g(–1), respectively, which are in agreement with the order of the polarity (low to high) of pesticides. Adsorption capacities indicated that the NFMBC preferably removed low-polarity pesticides from water sources. Since pineapple leaves provide fibers and NFMs for materials development, this study should promote an extended agro-waste utilization approach and full-cycle resource management in pineapple fields. |
format | Online Article Text |
id | pubmed-10373191 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-103731912023-07-28 Biochar Derived from Pineapple Leaf Non-Fibrous Materials and Its Adsorption Capability for Pesticides Srikhaow, Assadawoot Win, Ei Ei Amornsakchai, Taweechai Kiatsiriroat, Tanongkiat Kajitvichyanukul, Puangrat Smith, Siwaporn M. ACS Omega [Image: see text] Non-fibrous materials (NFMs) are typically discarded during pineapple leaf fiber processing. The underutilized NFM waste was proposed for use in this work as a raw material for the production of biochar . The removal of pesticides (acetamiprid, imidacloprid, or methomyl) from water was then investigated using the NFM derived biochar (NFMBC). The pseudo-second-order kinetic data suggested chemisorption of pesticide on NFMBC. While acetamiprid or imidacloprid adsorption on NFMBC occurred primarily via multi-layered adsorption (best fitted with the Freundlich isotherms), the Sips adsorption isotherms matched with the experimental data, implying heterogeneous adsorption of methomyl on the biochar surface. The adsorption capacities for acetamiprid, methomyl, and imidacloprid are 82.18, 36.16, and 28.98 mg g(–1), respectively, which are in agreement with the order of the polarity (low to high) of pesticides. Adsorption capacities indicated that the NFMBC preferably removed low-polarity pesticides from water sources. Since pineapple leaves provide fibers and NFMs for materials development, this study should promote an extended agro-waste utilization approach and full-cycle resource management in pineapple fields. American Chemical Society 2023-07-11 /pmc/articles/PMC10373191/ /pubmed/37521671 http://dx.doi.org/10.1021/acsomega.3c02328 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Srikhaow, Assadawoot Win, Ei Ei Amornsakchai, Taweechai Kiatsiriroat, Tanongkiat Kajitvichyanukul, Puangrat Smith, Siwaporn M. Biochar Derived from Pineapple Leaf Non-Fibrous Materials and Its Adsorption Capability for Pesticides |
title | Biochar Derived
from Pineapple Leaf Non-Fibrous Materials
and Its Adsorption Capability for Pesticides |
title_full | Biochar Derived
from Pineapple Leaf Non-Fibrous Materials
and Its Adsorption Capability for Pesticides |
title_fullStr | Biochar Derived
from Pineapple Leaf Non-Fibrous Materials
and Its Adsorption Capability for Pesticides |
title_full_unstemmed | Biochar Derived
from Pineapple Leaf Non-Fibrous Materials
and Its Adsorption Capability for Pesticides |
title_short | Biochar Derived
from Pineapple Leaf Non-Fibrous Materials
and Its Adsorption Capability for Pesticides |
title_sort | biochar derived
from pineapple leaf non-fibrous materials
and its adsorption capability for pesticides |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10373191/ https://www.ncbi.nlm.nih.gov/pubmed/37521671 http://dx.doi.org/10.1021/acsomega.3c02328 |
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