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Some Remarks on the Boundary of Thermodynamic Stability

In this paper, we have considered some elements of the classical phenomenological theory of thermodynamic stability, which seem controversial and ambiguous. The main focus is on the conditions of the stability boundary; a new version of the derivation of the relations defining the specified boundary...

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Detalles Bibliográficos
Autores principales: Toikka, Alexander, Misikov, Georgii, Toikka, Maria
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10378046/
https://www.ncbi.nlm.nih.gov/pubmed/37509916
http://dx.doi.org/10.3390/e25070969
Descripción
Sumario:In this paper, we have considered some elements of the classical phenomenological theory of thermodynamic stability, which seem controversial and ambiguous. The main focus is on the conditions of the stability boundary; a new version of the derivation of the relations defining the specified boundary is proposed. Although the final results, in general, coincide with the classical relations, the described approach, from our point of view, provides a clearer and more accurate idea of the stability conditions and their boundaries.