Some Remarks on the Boundary of Thermodynamic Stability

In this paper, we have considered some elements of the classical phenomenological theory of thermodynamic stability, which seem controversial and ambiguous. The main focus is on the conditions of the stability boundary; a new version of the derivation of the relations defining the specified boundary...

Descripción completa

Detalles Bibliográficos
Autores principales: Toikka, Alexander, Misikov, Georgii, Toikka, Maria
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Opinion
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10378046/
https://www.ncbi.nlm.nih.gov/pubmed/37509916
http://dx.doi.org/10.3390/e25070969
_version_ 1785079668840333312
author Toikka, Alexander
Misikov, Georgii
Toikka, Maria
author_facet Toikka, Alexander
Misikov, Georgii
Toikka, Maria
author_sort Toikka, Alexander
collection PubMed
description In this paper, we have considered some elements of the classical phenomenological theory of thermodynamic stability, which seem controversial and ambiguous. The main focus is on the conditions of the stability boundary; a new version of the derivation of the relations defining the specified boundary is proposed. Although the final results, in general, coincide with the classical relations, the described approach, from our point of view, provides a clearer and more accurate idea of the stability conditions and their boundaries.
format Online
Article
Text
id pubmed-10378046
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-103780462023-07-29 Some Remarks on the Boundary of Thermodynamic Stability Toikka, Alexander Misikov, Georgii Toikka, Maria Entropy (Basel) Opinion In this paper, we have considered some elements of the classical phenomenological theory of thermodynamic stability, which seem controversial and ambiguous. The main focus is on the conditions of the stability boundary; a new version of the derivation of the relations defining the specified boundary is proposed. Although the final results, in general, coincide with the classical relations, the described approach, from our point of view, provides a clearer and more accurate idea of the stability conditions and their boundaries. MDPI 2023-06-23 /pmc/articles/PMC10378046/ /pubmed/37509916 http://dx.doi.org/10.3390/e25070969 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Opinion
Toikka, Alexander
Misikov, Georgii
Toikka, Maria
Some Remarks on the Boundary of Thermodynamic Stability
title Some Remarks on the Boundary of Thermodynamic Stability
title_full Some Remarks on the Boundary of Thermodynamic Stability
title_fullStr Some Remarks on the Boundary of Thermodynamic Stability
title_full_unstemmed Some Remarks on the Boundary of Thermodynamic Stability
title_short Some Remarks on the Boundary of Thermodynamic Stability
title_sort some remarks on the boundary of thermodynamic stability
topic Opinion
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10378046/
https://www.ncbi.nlm.nih.gov/pubmed/37509916
http://dx.doi.org/10.3390/e25070969
work_keys_str_mv AT toikkaalexander someremarksontheboundaryofthermodynamicstability
AT misikovgeorgii someremarksontheboundaryofthermodynamicstability
AT toikkamaria someremarksontheboundaryofthermodynamicstability

Ejemplares similares