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Quantitative Description of Isomorphism in the Series of Simple Compounds

The introduction of the notion of energy change resulting from the ion exchange in apatites leads to the question: how can some simple isomorphic series be described using the mentioned idea? We concentrated on the simple isomorphic series of compounds: apatite, bioapatite, calcite, aragonite, celes...

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Autores principales: Kuczumow, Andrzej, Gorzelak, Mieczysław, Kosiński, Jakub, Lasota, Agnieszka, Szabelska, Anna, Blicharski, Tomasz, Gągała, Jacek, Wawrzyniak, Jolanta, Jarzębski, Maciej, Jabłoński, Mirosław
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10379828/
https://www.ncbi.nlm.nih.gov/pubmed/37511085
http://dx.doi.org/10.3390/ijms241411324
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author Kuczumow, Andrzej
Gorzelak, Mieczysław
Kosiński, Jakub
Lasota, Agnieszka
Szabelska, Anna
Blicharski, Tomasz
Gągała, Jacek
Wawrzyniak, Jolanta
Jarzębski, Maciej
Jabłoński, Mirosław
author_facet Kuczumow, Andrzej
Gorzelak, Mieczysław
Kosiński, Jakub
Lasota, Agnieszka
Szabelska, Anna
Blicharski, Tomasz
Gągała, Jacek
Wawrzyniak, Jolanta
Jarzębski, Maciej
Jabłoński, Mirosław
author_sort Kuczumow, Andrzej
collection PubMed
description The introduction of the notion of energy change resulting from the ion exchange in apatites leads to the question: how can some simple isomorphic series be described using the mentioned idea? We concentrated on the simple isomorphic series of compounds: apatite, bioapatite, calcite, aragonite, celestine, K-, Zn- and Cu-Tutton’s salts. It was demonstrated in all the series, except Tutton’s salts, that the change in energy and the change in the crystal cell volume are, in a simple way, dependent on the change in the ionic radii of the introduced ions. The linear relationships between the variations in energy and in the universal crystallographic dimension d were derived from the earlier equations and proven based on available data. In many cases, except the Tutton’s salts, linear dependence was discovered between the change in energy and the sinus of universal angle Θ, corresponding to the change in momentum transfer. In the same cases, linear dependencies were observed between the energy changes and the changes in the volumes of crystallographic cells, and mutually between changes in the crystallographic cell volume V, crystallographic dimension d, and diffraction angle Θ.
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spelling pubmed-103798282023-07-29 Quantitative Description of Isomorphism in the Series of Simple Compounds Kuczumow, Andrzej Gorzelak, Mieczysław Kosiński, Jakub Lasota, Agnieszka Szabelska, Anna Blicharski, Tomasz Gągała, Jacek Wawrzyniak, Jolanta Jarzębski, Maciej Jabłoński, Mirosław Int J Mol Sci Article The introduction of the notion of energy change resulting from the ion exchange in apatites leads to the question: how can some simple isomorphic series be described using the mentioned idea? We concentrated on the simple isomorphic series of compounds: apatite, bioapatite, calcite, aragonite, celestine, K-, Zn- and Cu-Tutton’s salts. It was demonstrated in all the series, except Tutton’s salts, that the change in energy and the change in the crystal cell volume are, in a simple way, dependent on the change in the ionic radii of the introduced ions. The linear relationships between the variations in energy and in the universal crystallographic dimension d were derived from the earlier equations and proven based on available data. In many cases, except the Tutton’s salts, linear dependence was discovered between the change in energy and the sinus of universal angle Θ, corresponding to the change in momentum transfer. In the same cases, linear dependencies were observed between the energy changes and the changes in the volumes of crystallographic cells, and mutually between changes in the crystallographic cell volume V, crystallographic dimension d, and diffraction angle Θ. MDPI 2023-07-11 /pmc/articles/PMC10379828/ /pubmed/37511085 http://dx.doi.org/10.3390/ijms241411324 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Kuczumow, Andrzej
Gorzelak, Mieczysław
Kosiński, Jakub
Lasota, Agnieszka
Szabelska, Anna
Blicharski, Tomasz
Gągała, Jacek
Wawrzyniak, Jolanta
Jarzębski, Maciej
Jabłoński, Mirosław
Quantitative Description of Isomorphism in the Series of Simple Compounds
title Quantitative Description of Isomorphism in the Series of Simple Compounds
title_full Quantitative Description of Isomorphism in the Series of Simple Compounds
title_fullStr Quantitative Description of Isomorphism in the Series of Simple Compounds
title_full_unstemmed Quantitative Description of Isomorphism in the Series of Simple Compounds
title_short Quantitative Description of Isomorphism in the Series of Simple Compounds
title_sort quantitative description of isomorphism in the series of simple compounds
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10379828/
https://www.ncbi.nlm.nih.gov/pubmed/37511085
http://dx.doi.org/10.3390/ijms241411324
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