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Testing the Performance of the Azo-Polyimide Supramolecular Systems as Substrate for Sensors Based on Platinum Electrodes

Azo-polyimide films with supramolecular structure were obtained by casting onto glass plates a mixture based on polyamidic acid and different quantities of azochromophore, followed by thermal treatment to realize the final azo-polyimide structure. The dielectric characteristics of the supramolecular...

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Autores principales: Sava, Ion, Asandulesa, Mihai, Barzic, Andreea Irina, Albu, Raluca Marinica, Stoica, Iuliana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10383144/
https://www.ncbi.nlm.nih.gov/pubmed/37512255
http://dx.doi.org/10.3390/ma16144980
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author Sava, Ion
Asandulesa, Mihai
Barzic, Andreea Irina
Albu, Raluca Marinica
Stoica, Iuliana
author_facet Sava, Ion
Asandulesa, Mihai
Barzic, Andreea Irina
Albu, Raluca Marinica
Stoica, Iuliana
author_sort Sava, Ion
collection PubMed
description Azo-polyimide films with supramolecular structure were obtained by casting onto glass plates a mixture based on polyamidic acid and different quantities of azochromophore, followed by thermal treatment to realize the final azo-polyimide structure. The dielectric characteristics of the supramolecular structure of polymer films were investigated by broad-band dielectric spectroscopy measurements at different temperatures and frequencies. The free-standing films proved to be flexible and tough and maintained their integrity after repeated bending. The work of adhesion at the polymer/platinum interface was calculated after the evaluation of the surface energy parameters before and after plasma treatment. Atomic force microscopy was used to image the surface morphology, the evolution of the roughness parameters, and the adhesion force between the platinum-covered tip and the polymer surface, registered at the nanoscale with the quantity of the azo dye introduced in the system. The simulation of the columnar growth of a platinum layer was made to provide information about the deposition parameters that should be used for optimal results in the deposition of platinum electrodes for sensors.
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spelling pubmed-103831442023-07-30 Testing the Performance of the Azo-Polyimide Supramolecular Systems as Substrate for Sensors Based on Platinum Electrodes Sava, Ion Asandulesa, Mihai Barzic, Andreea Irina Albu, Raluca Marinica Stoica, Iuliana Materials (Basel) Article Azo-polyimide films with supramolecular structure were obtained by casting onto glass plates a mixture based on polyamidic acid and different quantities of azochromophore, followed by thermal treatment to realize the final azo-polyimide structure. The dielectric characteristics of the supramolecular structure of polymer films were investigated by broad-band dielectric spectroscopy measurements at different temperatures and frequencies. The free-standing films proved to be flexible and tough and maintained their integrity after repeated bending. The work of adhesion at the polymer/platinum interface was calculated after the evaluation of the surface energy parameters before and after plasma treatment. Atomic force microscopy was used to image the surface morphology, the evolution of the roughness parameters, and the adhesion force between the platinum-covered tip and the polymer surface, registered at the nanoscale with the quantity of the azo dye introduced in the system. The simulation of the columnar growth of a platinum layer was made to provide information about the deposition parameters that should be used for optimal results in the deposition of platinum electrodes for sensors. MDPI 2023-07-13 /pmc/articles/PMC10383144/ /pubmed/37512255 http://dx.doi.org/10.3390/ma16144980 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Sava, Ion
Asandulesa, Mihai
Barzic, Andreea Irina
Albu, Raluca Marinica
Stoica, Iuliana
Testing the Performance of the Azo-Polyimide Supramolecular Systems as Substrate for Sensors Based on Platinum Electrodes
title Testing the Performance of the Azo-Polyimide Supramolecular Systems as Substrate for Sensors Based on Platinum Electrodes
title_full Testing the Performance of the Azo-Polyimide Supramolecular Systems as Substrate for Sensors Based on Platinum Electrodes
title_fullStr Testing the Performance of the Azo-Polyimide Supramolecular Systems as Substrate for Sensors Based on Platinum Electrodes
title_full_unstemmed Testing the Performance of the Azo-Polyimide Supramolecular Systems as Substrate for Sensors Based on Platinum Electrodes
title_short Testing the Performance of the Azo-Polyimide Supramolecular Systems as Substrate for Sensors Based on Platinum Electrodes
title_sort testing the performance of the azo-polyimide supramolecular systems as substrate for sensors based on platinum electrodes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10383144/
https://www.ncbi.nlm.nih.gov/pubmed/37512255
http://dx.doi.org/10.3390/ma16144980
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