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Paraffin–Peloid Formulations from Copahue: Processing, Characterization, and Application

The Copahue Thermal Center, situated in Neuquén, Argentina, produces natural and matured peloids, which are employed in the prevention and treatment of various osteoarticular and dermatological disorders. The presence of sulfur as a constituent and its thermotherapeutic potential constitute the prim...

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Autores principales: Sanchez, Micaela A., Baschini, Miria T., Pozo, Manuel, Gramisci, Betina R., Roca Jalil, María E., Vela, María L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10386061/
https://www.ncbi.nlm.nih.gov/pubmed/37512336
http://dx.doi.org/10.3390/ma16145062
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author Sanchez, Micaela A.
Baschini, Miria T.
Pozo, Manuel
Gramisci, Betina R.
Roca Jalil, María E.
Vela, María L.
author_facet Sanchez, Micaela A.
Baschini, Miria T.
Pozo, Manuel
Gramisci, Betina R.
Roca Jalil, María E.
Vela, María L.
author_sort Sanchez, Micaela A.
collection PubMed
description The Copahue Thermal Center, situated in Neuquén, Argentina, produces natural and matured peloids, which are employed in the prevention and treatment of various osteoarticular and dermatological disorders. The presence of sulfur as a constituent and its thermotherapeutic potential constitute the primary strengths of these peloids. Nevertheless, accessing Copahue is challenging due to its distance from densely populated centers and the snow cover during the winter months in the southern hemisphere. Therefore, in order to propose a material that can be utilized year-round in any location, a mudpack was obtained by combining medicinal paraffin with dehydrated Copahue peloids, with concentrations evaluated up to 10% w/w. This mudpack was analyzed through X-ray diffraction, which detected the presence of sulfur, the most important component of Copahue’s peloids. Through IR spectroscopy, the signals that identify medicinal paraffin were clearly observed, and for concentrations of 6% and 10% peloid in the material, it was possible to detect the presence of mineral clay components associated with Si-O stretching vibrations at around 1041 cm(−1). The low values of luminosity and grey tonality obtained for the mudpack contributed to patient acceptability and the absorption of electromagnetic radiation. The experimental cooling rate, calculated using the ratio of the temperature variation (∆T) with respect to the time variation (∆t) in each interval of the experimental curve, was determined to be 0.6 °C·min(−1) for both paraffin and the mudpack. However, for peloids, higher values ranging from 0.6 to 4.8 °C·min(−1) were obtained. This suggests that the mudpack mixtures have a slower heat release, which is a desirable property for their use as a thermotherapeutic agent. Considering the reusability of the mudpack, its stability was evaluated after 10 cycles of cooling and heating through XRD, DSC, and FTIR tests, resulting in a system that retains its properties. The formulation of the obtained mudpack is promising for the development of these materials on a larger scale.
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spelling pubmed-103860612023-07-30 Paraffin–Peloid Formulations from Copahue: Processing, Characterization, and Application Sanchez, Micaela A. Baschini, Miria T. Pozo, Manuel Gramisci, Betina R. Roca Jalil, María E. Vela, María L. Materials (Basel) Article The Copahue Thermal Center, situated in Neuquén, Argentina, produces natural and matured peloids, which are employed in the prevention and treatment of various osteoarticular and dermatological disorders. The presence of sulfur as a constituent and its thermotherapeutic potential constitute the primary strengths of these peloids. Nevertheless, accessing Copahue is challenging due to its distance from densely populated centers and the snow cover during the winter months in the southern hemisphere. Therefore, in order to propose a material that can be utilized year-round in any location, a mudpack was obtained by combining medicinal paraffin with dehydrated Copahue peloids, with concentrations evaluated up to 10% w/w. This mudpack was analyzed through X-ray diffraction, which detected the presence of sulfur, the most important component of Copahue’s peloids. Through IR spectroscopy, the signals that identify medicinal paraffin were clearly observed, and for concentrations of 6% and 10% peloid in the material, it was possible to detect the presence of mineral clay components associated with Si-O stretching vibrations at around 1041 cm(−1). The low values of luminosity and grey tonality obtained for the mudpack contributed to patient acceptability and the absorption of electromagnetic radiation. The experimental cooling rate, calculated using the ratio of the temperature variation (∆T) with respect to the time variation (∆t) in each interval of the experimental curve, was determined to be 0.6 °C·min(−1) for both paraffin and the mudpack. However, for peloids, higher values ranging from 0.6 to 4.8 °C·min(−1) were obtained. This suggests that the mudpack mixtures have a slower heat release, which is a desirable property for their use as a thermotherapeutic agent. Considering the reusability of the mudpack, its stability was evaluated after 10 cycles of cooling and heating through XRD, DSC, and FTIR tests, resulting in a system that retains its properties. The formulation of the obtained mudpack is promising for the development of these materials on a larger scale. MDPI 2023-07-18 /pmc/articles/PMC10386061/ /pubmed/37512336 http://dx.doi.org/10.3390/ma16145062 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Sanchez, Micaela A.
Baschini, Miria T.
Pozo, Manuel
Gramisci, Betina R.
Roca Jalil, María E.
Vela, María L.
Paraffin–Peloid Formulations from Copahue: Processing, Characterization, and Application
title Paraffin–Peloid Formulations from Copahue: Processing, Characterization, and Application
title_full Paraffin–Peloid Formulations from Copahue: Processing, Characterization, and Application
title_fullStr Paraffin–Peloid Formulations from Copahue: Processing, Characterization, and Application
title_full_unstemmed Paraffin–Peloid Formulations from Copahue: Processing, Characterization, and Application
title_short Paraffin–Peloid Formulations from Copahue: Processing, Characterization, and Application
title_sort paraffin–peloid formulations from copahue: processing, characterization, and application
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10386061/
https://www.ncbi.nlm.nih.gov/pubmed/37512336
http://dx.doi.org/10.3390/ma16145062
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