Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes

A mild, visible-light-induced, regioselective cascade sulfonylation-cyclization of 1,5-dienes with sulfonyl chlorides through the intermolecular radical addition/cyclization of alkenes C(sp(2))-H was developed. This procedure proceeds well and affords a mild and efficient route to a range of monosul...

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Detalles Bibliográficos
Autores principales: Ding, Ran, Li, Liang, Yu, Ya-Ting, Zhang, Bing, Wang, Pei-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10386375/
https://www.ncbi.nlm.nih.gov/pubmed/37513345
http://dx.doi.org/10.3390/molecules28145473
Descripción
Sumario:A mild, visible-light-induced, regioselective cascade sulfonylation-cyclization of 1,5-dienes with sulfonyl chlorides through the intermolecular radical addition/cyclization of alkenes C(sp(2))-H was developed. This procedure proceeds well and affords a mild and efficient route to a range of monosulfonylated pyrrolin-2-ones at room temperatures.

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