Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes

A mild, visible-light-induced, regioselective cascade sulfonylation-cyclization of 1,5-dienes with sulfonyl chlorides through the intermolecular radical addition/cyclization of alkenes C(sp(2))-H was developed. This procedure proceeds well and affords a mild and efficient route to a range of monosul...

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Detalles Bibliográficos
Autores principales: Ding, Ran, Li, Liang, Yu, Ya-Ting, Zhang, Bing, Wang, Pei-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10386375/
https://www.ncbi.nlm.nih.gov/pubmed/37513345
http://dx.doi.org/10.3390/molecules28145473
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author Ding, Ran
Li, Liang
Yu, Ya-Ting
Zhang, Bing
Wang, Pei-Long
author_facet Ding, Ran
Li, Liang
Yu, Ya-Ting
Zhang, Bing
Wang, Pei-Long
author_sort Ding, Ran
collection PubMed
description A mild, visible-light-induced, regioselective cascade sulfonylation-cyclization of 1,5-dienes with sulfonyl chlorides through the intermolecular radical addition/cyclization of alkenes C(sp(2))-H was developed. This procedure proceeds well and affords a mild and efficient route to a range of monosulfonylated pyrrolin-2-ones at room temperatures.
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spelling pubmed-103863752023-07-30 Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes Ding, Ran Li, Liang Yu, Ya-Ting Zhang, Bing Wang, Pei-Long Molecules Article A mild, visible-light-induced, regioselective cascade sulfonylation-cyclization of 1,5-dienes with sulfonyl chlorides through the intermolecular radical addition/cyclization of alkenes C(sp(2))-H was developed. This procedure proceeds well and affords a mild and efficient route to a range of monosulfonylated pyrrolin-2-ones at room temperatures. MDPI 2023-07-17 /pmc/articles/PMC10386375/ /pubmed/37513345 http://dx.doi.org/10.3390/molecules28145473 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ding, Ran
Li, Liang
Yu, Ya-Ting
Zhang, Bing
Wang, Pei-Long
Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes
title Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes
title_full Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes
title_fullStr Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes
title_full_unstemmed Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes
title_short Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes
title_sort photoredox-catalyzed synthesis of 3-sulfonylated pyrrolin-2-ones via a regioselective tandem sulfonylation cyclization of 1,5-dienes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10386375/
https://www.ncbi.nlm.nih.gov/pubmed/37513345
http://dx.doi.org/10.3390/molecules28145473
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