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Surfactant incorporated preyssler polyoxoanion: a transition metal substituted Mo-PHP complex and its applications

The complex was prepared with preyssler polyoxoanion and transition metal (Mo), a cationic surfactant as a connector. It has tuneable physical and chemical potential which has been exploited to study novel properties. A new technique of shock wave impulses is also used on the Mo-PHP complex. Extensi...

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Autores principales: SAMANNAN, Bharath, SELVAM, Jothi, LIN, Yi-Li, PETER, Praveen, THAVASIKANI, Jeyabalan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Scientific and Technological Research Council of Turkey (TUBITAK) 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10387894/
https://www.ncbi.nlm.nih.gov/pubmed/37528927
http://dx.doi.org/10.55730/1300-0527.3543
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author SAMANNAN, Bharath
SELVAM, Jothi
LIN, Yi-Li
PETER, Praveen
THAVASIKANI, Jeyabalan
author_facet SAMANNAN, Bharath
SELVAM, Jothi
LIN, Yi-Li
PETER, Praveen
THAVASIKANI, Jeyabalan
author_sort SAMANNAN, Bharath
collection PubMed
description The complex was prepared with preyssler polyoxoanion and transition metal (Mo), a cationic surfactant as a connector. It has tuneable physical and chemical potential which has been exploited to study novel properties. A new technique of shock wave impulses is also used on the Mo-PHP complex. Extensive use of cationic surfactants could impact accumulation in the environment set off the surfacing of bacterial resistance. Due to the electrostatic binding to bacterial surface, the hydrophobic parts of cationic surfactants tend to penetrate bacterial cell walls and may cause membrane lysis and bacteria death. The surfactant-supported and direct release of metal ions from P(5)W(29)Mo against bacterial resistance has been explained schematically. The dielectric study helps to understand the dissociation of cations that generate polarons and the hopping mechanism with neighbouring vacant atomic sites. Structural analysis confirms the formation of cationic surfactant incorporated polyoxoanion (Mo-PHP). A hexagonal shape-like structure for the PHP complex has been observed. The Mo-incorporated PHP complex was characterized using UV-visible (UV), Fourier Transform-infrared (IR), Raman spectra, scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD) techniques.
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spelling pubmed-103878942023-08-01 Surfactant incorporated preyssler polyoxoanion: a transition metal substituted Mo-PHP complex and its applications SAMANNAN, Bharath SELVAM, Jothi LIN, Yi-Li PETER, Praveen THAVASIKANI, Jeyabalan Turk J Chem Research Article The complex was prepared with preyssler polyoxoanion and transition metal (Mo), a cationic surfactant as a connector. It has tuneable physical and chemical potential which has been exploited to study novel properties. A new technique of shock wave impulses is also used on the Mo-PHP complex. Extensive use of cationic surfactants could impact accumulation in the environment set off the surfacing of bacterial resistance. Due to the electrostatic binding to bacterial surface, the hydrophobic parts of cationic surfactants tend to penetrate bacterial cell walls and may cause membrane lysis and bacteria death. The surfactant-supported and direct release of metal ions from P(5)W(29)Mo against bacterial resistance has been explained schematically. The dielectric study helps to understand the dissociation of cations that generate polarons and the hopping mechanism with neighbouring vacant atomic sites. Structural analysis confirms the formation of cationic surfactant incorporated polyoxoanion (Mo-PHP). A hexagonal shape-like structure for the PHP complex has been observed. The Mo-incorporated PHP complex was characterized using UV-visible (UV), Fourier Transform-infrared (IR), Raman spectra, scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD) techniques. Scientific and Technological Research Council of Turkey (TUBITAK) 2023-01-06 /pmc/articles/PMC10387894/ /pubmed/37528927 http://dx.doi.org/10.55730/1300-0527.3543 Text en © TÜBİTAK https://creativecommons.org/licenses/by/4.0/This work is licensed under a Creative Commons Attribution 4.0 International License.
spellingShingle Research Article
SAMANNAN, Bharath
SELVAM, Jothi
LIN, Yi-Li
PETER, Praveen
THAVASIKANI, Jeyabalan
Surfactant incorporated preyssler polyoxoanion: a transition metal substituted Mo-PHP complex and its applications
title Surfactant incorporated preyssler polyoxoanion: a transition metal substituted Mo-PHP complex and its applications
title_full Surfactant incorporated preyssler polyoxoanion: a transition metal substituted Mo-PHP complex and its applications
title_fullStr Surfactant incorporated preyssler polyoxoanion: a transition metal substituted Mo-PHP complex and its applications
title_full_unstemmed Surfactant incorporated preyssler polyoxoanion: a transition metal substituted Mo-PHP complex and its applications
title_short Surfactant incorporated preyssler polyoxoanion: a transition metal substituted Mo-PHP complex and its applications
title_sort surfactant incorporated preyssler polyoxoanion: a transition metal substituted mo-php complex and its applications
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10387894/
https://www.ncbi.nlm.nih.gov/pubmed/37528927
http://dx.doi.org/10.55730/1300-0527.3543
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