Cargando…

Magnetically Induced Catalytic Reduction of Biomass-Derived Oxygenated Compounds in Water

[Image: see text] The development of energetically efficient processes for the aqueous reduction of biomass-derived compounds into chemicals is key for the optimal transformation of biomass. Herein we report an early example of the reduction of biomass-derived oxygenated compounds in water by magnet...

Descripción completa

Detalles Bibliográficos
Autores principales: Cerezo-Navarrete, Christian, Marin, Irene Mustieles, García-Miquel, Héctor, Corma, Avelino, Chaudret, Bruno, Martínez-Prieto, Luis M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10388291/
https://www.ncbi.nlm.nih.gov/pubmed/37528952
http://dx.doi.org/10.1021/acscatal.2c01696
_version_ 1785082081630486528
author Cerezo-Navarrete, Christian
Marin, Irene Mustieles
García-Miquel, Héctor
Corma, Avelino
Chaudret, Bruno
Martínez-Prieto, Luis M.
author_facet Cerezo-Navarrete, Christian
Marin, Irene Mustieles
García-Miquel, Héctor
Corma, Avelino
Chaudret, Bruno
Martínez-Prieto, Luis M.
author_sort Cerezo-Navarrete, Christian
collection PubMed
description [Image: see text] The development of energetically efficient processes for the aqueous reduction of biomass-derived compounds into chemicals is key for the optimal transformation of biomass. Herein we report an early example of the reduction of biomass-derived oxygenated compounds in water by magnetically induced catalysis. Non-coated and carbon-coated core–shell FeCo@Ni magnetic nanoparticles were used as the heating agent and the catalyst simultaneously. In this way it was possible to control the product distribution by adjusting the field amplitude applied during the magnetic catalysis, opening a precedent for this type of catalysis. Finally, the encapsulation of the magnetic nanoparticles in carbon (FeCo@Ni@C) strongly improved the stability of the magnetic catalyst in solution, making its reuse possible up to at least eight times in dioxane and four times in water.
format Online
Article
Text
id pubmed-10388291
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-103882912023-08-01 Magnetically Induced Catalytic Reduction of Biomass-Derived Oxygenated Compounds in Water Cerezo-Navarrete, Christian Marin, Irene Mustieles García-Miquel, Héctor Corma, Avelino Chaudret, Bruno Martínez-Prieto, Luis M. ACS Catal [Image: see text] The development of energetically efficient processes for the aqueous reduction of biomass-derived compounds into chemicals is key for the optimal transformation of biomass. Herein we report an early example of the reduction of biomass-derived oxygenated compounds in water by magnetically induced catalysis. Non-coated and carbon-coated core–shell FeCo@Ni magnetic nanoparticles were used as the heating agent and the catalyst simultaneously. In this way it was possible to control the product distribution by adjusting the field amplitude applied during the magnetic catalysis, opening a precedent for this type of catalysis. Finally, the encapsulation of the magnetic nanoparticles in carbon (FeCo@Ni@C) strongly improved the stability of the magnetic catalyst in solution, making its reuse possible up to at least eight times in dioxane and four times in water. American Chemical Society 2022-07-01 /pmc/articles/PMC10388291/ /pubmed/37528952 http://dx.doi.org/10.1021/acscatal.2c01696 Text en © 2022 American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Cerezo-Navarrete, Christian
Marin, Irene Mustieles
García-Miquel, Héctor
Corma, Avelino
Chaudret, Bruno
Martínez-Prieto, Luis M.
Magnetically Induced Catalytic Reduction of Biomass-Derived Oxygenated Compounds in Water
title Magnetically Induced Catalytic Reduction of Biomass-Derived Oxygenated Compounds in Water
title_full Magnetically Induced Catalytic Reduction of Biomass-Derived Oxygenated Compounds in Water
title_fullStr Magnetically Induced Catalytic Reduction of Biomass-Derived Oxygenated Compounds in Water
title_full_unstemmed Magnetically Induced Catalytic Reduction of Biomass-Derived Oxygenated Compounds in Water
title_short Magnetically Induced Catalytic Reduction of Biomass-Derived Oxygenated Compounds in Water
title_sort magnetically induced catalytic reduction of biomass-derived oxygenated compounds in water
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10388291/
https://www.ncbi.nlm.nih.gov/pubmed/37528952
http://dx.doi.org/10.1021/acscatal.2c01696
work_keys_str_mv AT cerezonavarretechristian magneticallyinducedcatalyticreductionofbiomassderivedoxygenatedcompoundsinwater
AT marinirenemustieles magneticallyinducedcatalyticreductionofbiomassderivedoxygenatedcompoundsinwater
AT garciamiquelhector magneticallyinducedcatalyticreductionofbiomassderivedoxygenatedcompoundsinwater
AT cormaavelino magneticallyinducedcatalyticreductionofbiomassderivedoxygenatedcompoundsinwater
AT chaudretbruno magneticallyinducedcatalyticreductionofbiomassderivedoxygenatedcompoundsinwater
AT martinezprietoluism magneticallyinducedcatalyticreductionofbiomassderivedoxygenatedcompoundsinwater