Developing Solution-Processed Distributed Bragg Reflectors for Microcavity Polariton Applications

[Image: see text] Improving the performance of organic optoelectronics has been under vigorous research for decades. Recently, polaritonics has been introduced as a technology that has the potential to improve the optical, electrical, and chemical properties of materials and devices. However, polaritons have been mainly studied in optical microcavities that are made by vacuum deposition processes, which are costly, unavailable to many, and incompatible with printed optoelectronics methods. Efforts toward the fabrication of polariton microcavities with solution-processed techniques have been utterly absent. Herein, we demonstrate for the first time strong light–matter coupling and polariton photoluminescence in an organic microcavity consisting of an aluminum mirror and a distributed Bragg reflector (DBR) made by sequential dip coating of titanium hydroxide/poly(vinyl alcohol) (TiOH/PVA) and Nafion films. To fabricate and develop the solution-processed DBRs and microcavities, we automatized a dip-coating device that allowed us to produce sub-100 nm films consistently over many dip-coating cycles. Owning to the solution-based nature of our DBRs, our results pave the way to the realization of polariton optoelectronic devices beyond physical deposition methods.