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High Quality Factor in Solution-Processed Inorganic Microcavities Embedding CsPbBr(3) Perovskite Nanocrystals

[Image: see text] Optical microcavities grant manipulation over light–matter interactions and light propagation, enabling the fabrication of foundational optical and optoelectronic components. However, the materials used for high-performing systems, mostly bulk inorganics, are typically costly, and...

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Autores principales: Bertucci, Simone, Escher, Andrea, Cirignano, Matilde, De Franco, Manuela, Locardi, Federico, Patrini, Maddalena, Comoretto, Davide, Lova, Paola, Di Stasio, Francesco
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10391615/
https://www.ncbi.nlm.nih.gov/pubmed/37533664
http://dx.doi.org/10.1021/acsaom.3c00157
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author Bertucci, Simone
Escher, Andrea
Cirignano, Matilde
De Franco, Manuela
Locardi, Federico
Patrini, Maddalena
Comoretto, Davide
Lova, Paola
Di Stasio, Francesco
author_facet Bertucci, Simone
Escher, Andrea
Cirignano, Matilde
De Franco, Manuela
Locardi, Federico
Patrini, Maddalena
Comoretto, Davide
Lova, Paola
Di Stasio, Francesco
author_sort Bertucci, Simone
collection PubMed
description [Image: see text] Optical microcavities grant manipulation over light–matter interactions and light propagation, enabling the fabrication of foundational optical and optoelectronic components. However, the materials used for high-performing systems, mostly bulk inorganics, are typically costly, and their processing is hardly scalable. In this work, we present an alternative way to fabricate planar optical resonators via solely solution processing while approaching the performances of conventional systems. Here, we couple fully solution-processed high dielectric contrast inorganic Bragg mirrors obtained by sol–gel deposition with the remarkable photoluminescence properties of CsPbBr(3) perovskite nanocrystals. The approach yields microcavities with a quality factor of ∼220, which is a record value for solution-processed inorganic structures, and a strong emission redistribution resulting in a 3-fold directional intensity enhancement.
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spelling pubmed-103916152023-08-02 High Quality Factor in Solution-Processed Inorganic Microcavities Embedding CsPbBr(3) Perovskite Nanocrystals Bertucci, Simone Escher, Andrea Cirignano, Matilde De Franco, Manuela Locardi, Federico Patrini, Maddalena Comoretto, Davide Lova, Paola Di Stasio, Francesco ACS Appl Opt Mater [Image: see text] Optical microcavities grant manipulation over light–matter interactions and light propagation, enabling the fabrication of foundational optical and optoelectronic components. However, the materials used for high-performing systems, mostly bulk inorganics, are typically costly, and their processing is hardly scalable. In this work, we present an alternative way to fabricate planar optical resonators via solely solution processing while approaching the performances of conventional systems. Here, we couple fully solution-processed high dielectric contrast inorganic Bragg mirrors obtained by sol–gel deposition with the remarkable photoluminescence properties of CsPbBr(3) perovskite nanocrystals. The approach yields microcavities with a quality factor of ∼220, which is a record value for solution-processed inorganic structures, and a strong emission redistribution resulting in a 3-fold directional intensity enhancement. American Chemical Society 2023-07-18 /pmc/articles/PMC10391615/ /pubmed/37533664 http://dx.doi.org/10.1021/acsaom.3c00157 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Bertucci, Simone
Escher, Andrea
Cirignano, Matilde
De Franco, Manuela
Locardi, Federico
Patrini, Maddalena
Comoretto, Davide
Lova, Paola
Di Stasio, Francesco
High Quality Factor in Solution-Processed Inorganic Microcavities Embedding CsPbBr(3) Perovskite Nanocrystals
title High Quality Factor in Solution-Processed Inorganic Microcavities Embedding CsPbBr(3) Perovskite Nanocrystals
title_full High Quality Factor in Solution-Processed Inorganic Microcavities Embedding CsPbBr(3) Perovskite Nanocrystals
title_fullStr High Quality Factor in Solution-Processed Inorganic Microcavities Embedding CsPbBr(3) Perovskite Nanocrystals
title_full_unstemmed High Quality Factor in Solution-Processed Inorganic Microcavities Embedding CsPbBr(3) Perovskite Nanocrystals
title_short High Quality Factor in Solution-Processed Inorganic Microcavities Embedding CsPbBr(3) Perovskite Nanocrystals
title_sort high quality factor in solution-processed inorganic microcavities embedding cspbbr(3) perovskite nanocrystals
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10391615/
https://www.ncbi.nlm.nih.gov/pubmed/37533664
http://dx.doi.org/10.1021/acsaom.3c00157
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