Cargando…

C–C bond formation via photocatalytic direct functionalization of simple alkanes

The direct functionalization of alkanes represents a very important challenge in the goal to develop more atom-efficient and clean C–C bond forming reactions. These processes, however, are hampered by the low reactivity of the aliphatic C–H bonds. Photocatalytic processes based on hydrogen atom tran...

Descripción completa

Detalles Bibliográficos
Autores principales:	Velasco-Rubio, Álvaro, Martínez-Balart, Pol, Álvarez-Constantino, Andrés M., Fañanás-Mastral, Martín
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10392964/ https://www.ncbi.nlm.nih.gov/pubmed/37417212 http://dx.doi.org/10.1039/d3cc02790b

Ejemplares similares

Direct C–H Allylation of Unactivated Alkanes by Cooperative W/Cu Photocatalysis
por: Martínez-Balart, Pol, et al.
Publicado: (2022)

Unstrained C–C bond activation and directed fluorination through photocatalytically-generated radical cations
por: Pitts, Cody Ross, et al.
Publicado: (2015)

Direct catalytic cross-coupling of alkenyllithium compounds
por: Hornillos, Valentín, et al.
Publicado: (2015)

Enantio‐ and Diastereoselective Copper‐Catalyzed Allylboration of Alkynes with Allylic gem‐Dichlorides
por: Chaves‐Pouso, Andrea, et al.
Publicado: (2022)

Copper-Catalyzed Enantioselective Borylative Allyl–Allyl Coupling of Allenes and Allylic gem-Dichlorides
por: Piñeiro-Suárez, Martín, et al.
Publicado: (2023)

Catalytic Lewis Base Additive Enables Selective Copper-Catalyzed Borylative α-C–H Allylation of Alicyclic Amines
por: Pérez-Saavedra, Borja, et al.
Publicado: (2022)

Organo-photocatalytic C–H bond oxidation: an operationally simple and scalable method to prepare ketones with ambient air
por: Nguyen, Ky, et al.
Publicado: (2023)

Photocatalytic C(sp(3)) radical generation via C–H, C–C, and C–X bond cleavage
por: Huang, Chia-Yu, et al.
Publicado: (2022)

Selective photocatalytic C–C bond cleavage under ambient conditions with earth abundant vanadium complexes
por: Gazi, Sarifuddin, et al.
Publicado: (2015)

Selective C–O bond formation via a photocatalytic radical coupling strategy: access to perfluoroalkoxylated (OR(F)) arenes and heteroarenes
por: Lee, Johnny W., et al.
Publicado: (2017)

Structural basis for enzymatic terminal C–H bond functionalization of alkanes
por: Chai, Jin, et al.
Publicado: (2023)

Recent trends in the direct oxyphosphorylation of C–C multiple bonds
por: Bakhtiary, Alireza, et al.
Publicado: (2020)

Formation and evolution of C–C, C–O, C[double bond, length as m-dash]O and C–N bonds in chemical reactions of prebiotic interest
por: Arias, Alejandro, et al.
Publicado: (2022)

Cu-catalyzed C–C bond formation of vinylidene cyclopropanes with carbon nucleophiles
por: Chen, Jichao, et al.
Publicado: (2019)

Ketones as directing groups in photocatalytic sp(3) C–H fluorination
por: Bume, Desta Doro, et al.
Publicado: (2017)

PIDA-mediated intramolecular oxidative C–N bond formation for the direct synthesis of quinoxalines from enaminones
por: Zhang, Hong, et al.
Publicado: (2019)

Strategies for the Photocatalytic Generation of Carbanion Equivalents for Reductant-Free C–C Bond Formations
por: Donabauer, Karsten, et al.
Publicado: (2020)

Cobalt-catalyzed C(sp(3))–H/C(sp(2))–H oxidative coupling between alkanes and benzamides
por: Li, Shuangjie, et al.
Publicado: (2018)

Photocatalytic carbanion generation from C–H bonds – reductant free Barbier/Grignard-type reactions
por: Berger, Anna Lucia, et al.
Publicado: (2019)

Aerobic C–C and C–O bond formation reactions mediated by high-valent nickel species
por: Smith, Sofia M., et al.
Publicado: (2019)

Reversible C–C bond formation at a triply cyclometallated platinum(iv) centre
por: Shaw, Paul A., et al.
Publicado: (2017)

Correction: Cu-catalyzed C–C bond formation of vinylidene cyclopropanes with carbon nucleophiles
por: Chen, Jichao, et al.
Publicado: (2020)

Palladium nanoparticles as efficient catalyst for C–S bond formation reactions
por: Zhang, Mei-Na, et al.
Publicado: (2020)

Consecutive C–F bond activation and C–F bond formation of heteroaromatics at rhodium: the peculiar role of FSi(OEt)(3)
por: Raza, A. L., et al.
Publicado: (2015)

Recent advances in direct trifluoromethylation of olefinic C–H bonds
por: Yang, Cao, et al.
Publicado: (2019)

Methods for direct C(sp(2))–H bonds azidation
por: Liu, Ying, et al.
Publicado: (2019)

Photocatalytic Activation of Saturated C–H Bond Over the CdS Mixed-Phase Under Visible Light Irradiation
por: She, Houde, et al.
Publicado: (2018)

Luminescent tungsten(vi) complexes as photocatalysts for light-driven C–C and C–B bond formation reactions
por: Yu, Daohong, et al.
Publicado: (2020)

Functionalisation of ethereal-based saturated heterocycles with concomitant aerobic C–H activation and C–C bond formation
por: Ahmed, Nehaal, et al.
Publicado: (2022)

Ultrafast C–C and C–N bond formation reactions in water microdroplets facilitated by the spontaneous generation of carbocations
por: Wang, Ting, et al.
Publicado: (2023)

Merging of the photocatalysis and copper catalysis in metal–organic frameworks for oxidative C–C bond formation
por: Shi, Dongying, et al.
Publicado: (2015)

Organocopper cross-coupling reaction for C–C bond formation on highly sterically hindered structures
por: Oi, Miku, et al.
Publicado: (2019)

Metal-free C–C bond formation via coupling of nitrile imines and boronic acids
por: Livingstone, Keith, et al.
Publicado: (2019)

Discovery of a simple iron catalyst reveals the intimate steps of C–H amination to form C–N bonds
por: Stroek, Wowa, et al.
Publicado: (2022)

Construction and performance of a simple and efficient g-C(3)N(4) photocatalytic hydrogen production system
por: Xu, Yun, et al.
Publicado: (2021)

New avenues for C–B bond formation via radical intermediates
por: Friese, Florian W., et al.
Publicado: (2019)

Decarboxylative cross-coupling reactions for P(O)–C bond formation
por: Hosseinian, Akram, et al.
Publicado: (2018)

Recent application of visible-light induced radicals in C–S bond formation
por: Srivastava, Vishal, et al.
Publicado: (2020)

Ligand-field transition-induced C–S bond formation from nickelacycles
por: Shin, Jeongcheol, et al.
Publicado: (2021)

Direct phosphorylation of benzylic C–H bonds under transition metal-free conditions forming sp(3)C–P bonds
por: Li, Qiang, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_556vs4rv5vt92rgia9nk39fao3