Cargando…

Exploring the properties of Dy(2)O(3)–Y(2)O(3) Co-activated telluro-borate glass: Structural, physical, optical, thermal, and mechanical properties

The successful application of glass-based materials in a wide range of scientific fields depends on the associated physical, optical, thermal, and mechanical properties. This article investigate the structural, Physical, thermal, optical, and mechanical properties of Dy(2)O(3), Y(2)O(3) co-activated...

Descripción completa

Detalles Bibliográficos
Autores principales: Thabit, Hammam Abdurabu, Ismail, Abd Khamim, Mhareb, M.H.A., Abdulmalik, D.A., I, Abdullahi, Al-Fakih, Abdo Mohammed, Alajerami, Y.S.M., S.Hashim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10393758/
https://www.ncbi.nlm.nih.gov/pubmed/37539187
http://dx.doi.org/10.1016/j.heliyon.2023.e18309
Descripción
Sumario:The successful application of glass-based materials in a wide range of scientific fields depends on the associated physical, optical, thermal, and mechanical properties. This article investigate the structural, Physical, thermal, optical, and mechanical properties of Dy(2)O(3), Y(2)O(3) co-activated telluro-borate glass developed using the melt-quenching method. The glassy quality and the elements component of the specimens were observed using XRD and EDX analyses. The addition of Y(2)O(3) rise the glass density from 2.956 to 3.303 g/cm(3) the refractive index from 2.5 to 2.7. These changes are due to the increase in polarizability and non-bridging oxygen (NBO). The photoluminescence (PL) spectra revealed a broad peak at 550 nm and additional weak emission peaks at 573 and 664 nm, respectively. While the observed broader peak can be linked to the convolution of Bi(3+) ions transitions corresponding to the non-centrosymmetric site respectively, the weak emission bands are due to (4)F(9/2) → (6)H(13/2) and (4)F(9/2) → (6)H(11/2) Dy(3+) transitions. Hence, the low symmetrical features of both Bi(3+) and Dy(3+) ions were confirmed. The increase in the Vickers hardness of the glass from 536.7 to 1366.9 indicates the influence of Y(2)O(3) addition on the mechanical properties of the glasses. The findings help to improve our understanding of the behaviour of the glass composition and its prospective applications in disciplines such as photonic, and laser optics.