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Valve turning towards on-cycle in cobalt-catalyzed Negishi-type cross-coupling

Ligands and additives are often utilized to stabilize low-valent catalytic metal species experimentally, while their role in suppressing metal deposition has been less studied. Herein, an on-cycle mechanism is reported for CoCl(2)bpy(2) catalyzed Negishi-type cross-coupling. A full catalytic cycle o...

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Detalles Bibliográficos
Autores principales: Luo, Xu, Yang, Dali, He, Xiaoqian, Wang, Shengchun, Zhang, Dongchao, Xu, Jiaxin, Pao, Chih-Wen, Chen, Jeng-Lung, Lee, Jyh-Fu, Cong, Hengjiang, Lan, Yu, Alhumade, Hesham, Cossy, Janine, Bai, Ruopeng, Chen, Yi-Hung, Yi, Hong, Lei, Aiwen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10397345/
https://www.ncbi.nlm.nih.gov/pubmed/37532729
http://dx.doi.org/10.1038/s41467-023-40269-y

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