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Optical properties of graphene oxide
The study of the optical properties of graphene oxide (GO) is crucial in designing functionalized GO materials with specific optical properties for various applications such as (bio) sensors, optoelectronics, and energy storage. The present work aims to investigate the electronic transitions, optica...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10397392/ https://www.ncbi.nlm.nih.gov/pubmed/37547907 http://dx.doi.org/10.3389/fchem.2023.1214072 |
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author | Tene, Talia Guevara, Marco Benalcázar Palacios, Freddy Morocho Barrionuevo, Tania Paulina Vacacela Gomez, Cristian Bellucci, Stefano |
author_facet | Tene, Talia Guevara, Marco Benalcázar Palacios, Freddy Morocho Barrionuevo, Tania Paulina Vacacela Gomez, Cristian Bellucci, Stefano |
author_sort | Tene, Talia |
collection | PubMed |
description | The study of the optical properties of graphene oxide (GO) is crucial in designing functionalized GO materials with specific optical properties for various applications such as (bio) sensors, optoelectronics, and energy storage. The present work aims to investigate the electronic transitions, optical bandgap, and absorption coefficient of GO under different conditions. Specifically, the study examines the effects of drying times ranging from 0 to 120 h while maintaining a fixed temperature of 80°C and low temperatures ranging from 40 [Formula: see text] to 100 [Formula: see text] , with a constant drying time of 24 h. Our findings indicate that exposing the GO sample to a drying time of up to 120 h at 80°C can lead to a reduction in the optical bandgap, decreasing it from 4.09 to 2.76 eV. The [Formula: see text] transition was found to be the most affected, shifting from approximately 230 nm at 0 h to 244 nm after 120 h of drying time. Absorption coefficients of 3140–5507 ml mg(−1) m(−1) were measured, which are similar to those reported for exfoliated graphene dispersions but up to two times higher, confirming the improved optical properties of GO. Our findings can provide insights into determining the optimal temperature and duration required for transforming GO into its reduced form for a specific application through extrapolation. The study is complemented by analyzing the elemental composition, surface morphology change, and electrical properties. |
format | Online Article Text |
id | pubmed-10397392 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Frontiers Media S.A. |
record_format | MEDLINE/PubMed |
spelling | pubmed-103973922023-08-04 Optical properties of graphene oxide Tene, Talia Guevara, Marco Benalcázar Palacios, Freddy Morocho Barrionuevo, Tania Paulina Vacacela Gomez, Cristian Bellucci, Stefano Front Chem Chemistry The study of the optical properties of graphene oxide (GO) is crucial in designing functionalized GO materials with specific optical properties for various applications such as (bio) sensors, optoelectronics, and energy storage. The present work aims to investigate the electronic transitions, optical bandgap, and absorption coefficient of GO under different conditions. Specifically, the study examines the effects of drying times ranging from 0 to 120 h while maintaining a fixed temperature of 80°C and low temperatures ranging from 40 [Formula: see text] to 100 [Formula: see text] , with a constant drying time of 24 h. Our findings indicate that exposing the GO sample to a drying time of up to 120 h at 80°C can lead to a reduction in the optical bandgap, decreasing it from 4.09 to 2.76 eV. The [Formula: see text] transition was found to be the most affected, shifting from approximately 230 nm at 0 h to 244 nm after 120 h of drying time. Absorption coefficients of 3140–5507 ml mg(−1) m(−1) were measured, which are similar to those reported for exfoliated graphene dispersions but up to two times higher, confirming the improved optical properties of GO. Our findings can provide insights into determining the optimal temperature and duration required for transforming GO into its reduced form for a specific application through extrapolation. The study is complemented by analyzing the elemental composition, surface morphology change, and electrical properties. Frontiers Media S.A. 2023-07-20 /pmc/articles/PMC10397392/ /pubmed/37547907 http://dx.doi.org/10.3389/fchem.2023.1214072 Text en Copyright © 2023 Tene, Guevara, Benalcázar Palacios, Morocho Barrionuevo, Vacacela Gomez and Bellucci. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
spellingShingle | Chemistry Tene, Talia Guevara, Marco Benalcázar Palacios, Freddy Morocho Barrionuevo, Tania Paulina Vacacela Gomez, Cristian Bellucci, Stefano Optical properties of graphene oxide |
title | Optical properties of graphene oxide |
title_full | Optical properties of graphene oxide |
title_fullStr | Optical properties of graphene oxide |
title_full_unstemmed | Optical properties of graphene oxide |
title_short | Optical properties of graphene oxide |
title_sort | optical properties of graphene oxide |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10397392/ https://www.ncbi.nlm.nih.gov/pubmed/37547907 http://dx.doi.org/10.3389/fchem.2023.1214072 |
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