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Optical properties of graphene oxide

The study of the optical properties of graphene oxide (GO) is crucial in designing functionalized GO materials with specific optical properties for various applications such as (bio) sensors, optoelectronics, and energy storage. The present work aims to investigate the electronic transitions, optica...

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Autores principales: Tene, Talia, Guevara, Marco, Benalcázar Palacios, Freddy, Morocho Barrionuevo, Tania Paulina, Vacacela Gomez, Cristian, Bellucci, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10397392/
https://www.ncbi.nlm.nih.gov/pubmed/37547907
http://dx.doi.org/10.3389/fchem.2023.1214072
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author Tene, Talia
Guevara, Marco
Benalcázar Palacios, Freddy
Morocho Barrionuevo, Tania Paulina
Vacacela Gomez, Cristian
Bellucci, Stefano
author_facet Tene, Talia
Guevara, Marco
Benalcázar Palacios, Freddy
Morocho Barrionuevo, Tania Paulina
Vacacela Gomez, Cristian
Bellucci, Stefano
author_sort Tene, Talia
collection PubMed
description The study of the optical properties of graphene oxide (GO) is crucial in designing functionalized GO materials with specific optical properties for various applications such as (bio) sensors, optoelectronics, and energy storage. The present work aims to investigate the electronic transitions, optical bandgap, and absorption coefficient of GO under different conditions. Specifically, the study examines the effects of drying times ranging from 0 to 120 h while maintaining a fixed temperature of 80°C and low temperatures ranging from 40 [Formula: see text] to 100 [Formula: see text] , with a constant drying time of 24 h. Our findings indicate that exposing the GO sample to a drying time of up to 120 h at 80°C can lead to a reduction in the optical bandgap, decreasing it from 4.09 to 2.76 eV. The [Formula: see text] transition was found to be the most affected, shifting from approximately 230 nm at 0 h to 244 nm after 120 h of drying time. Absorption coefficients of 3140–5507 ml mg(−1) m(−1) were measured, which are similar to those reported for exfoliated graphene dispersions but up to two times higher, confirming the improved optical properties of GO. Our findings can provide insights into determining the optimal temperature and duration required for transforming GO into its reduced form for a specific application through extrapolation. The study is complemented by analyzing the elemental composition, surface morphology change, and electrical properties.
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spelling pubmed-103973922023-08-04 Optical properties of graphene oxide Tene, Talia Guevara, Marco Benalcázar Palacios, Freddy Morocho Barrionuevo, Tania Paulina Vacacela Gomez, Cristian Bellucci, Stefano Front Chem Chemistry The study of the optical properties of graphene oxide (GO) is crucial in designing functionalized GO materials with specific optical properties for various applications such as (bio) sensors, optoelectronics, and energy storage. The present work aims to investigate the electronic transitions, optical bandgap, and absorption coefficient of GO under different conditions. Specifically, the study examines the effects of drying times ranging from 0 to 120 h while maintaining a fixed temperature of 80°C and low temperatures ranging from 40 [Formula: see text] to 100 [Formula: see text] , with a constant drying time of 24 h. Our findings indicate that exposing the GO sample to a drying time of up to 120 h at 80°C can lead to a reduction in the optical bandgap, decreasing it from 4.09 to 2.76 eV. The [Formula: see text] transition was found to be the most affected, shifting from approximately 230 nm at 0 h to 244 nm after 120 h of drying time. Absorption coefficients of 3140–5507 ml mg(−1) m(−1) were measured, which are similar to those reported for exfoliated graphene dispersions but up to two times higher, confirming the improved optical properties of GO. Our findings can provide insights into determining the optimal temperature and duration required for transforming GO into its reduced form for a specific application through extrapolation. The study is complemented by analyzing the elemental composition, surface morphology change, and electrical properties. Frontiers Media S.A. 2023-07-20 /pmc/articles/PMC10397392/ /pubmed/37547907 http://dx.doi.org/10.3389/fchem.2023.1214072 Text en Copyright © 2023 Tene, Guevara, Benalcázar Palacios, Morocho Barrionuevo, Vacacela Gomez and Bellucci. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Tene, Talia
Guevara, Marco
Benalcázar Palacios, Freddy
Morocho Barrionuevo, Tania Paulina
Vacacela Gomez, Cristian
Bellucci, Stefano
Optical properties of graphene oxide
title Optical properties of graphene oxide
title_full Optical properties of graphene oxide
title_fullStr Optical properties of graphene oxide
title_full_unstemmed Optical properties of graphene oxide
title_short Optical properties of graphene oxide
title_sort optical properties of graphene oxide
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10397392/
https://www.ncbi.nlm.nih.gov/pubmed/37547907
http://dx.doi.org/10.3389/fchem.2023.1214072
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