Cargando…

Impact of Bidentate Pyridyl-Mesoionic Carbene Ligands: Structural, (Spectro)Electrochemical, Photophysical, and Theoretical Investigations on Ruthenium(II) Complexes

[Image: see text] We present here new synthetic strategies for the isolation of a series of Ru(II) complexes with pyridyl-mesoionic carbene ligands (MIC) of the 1,2,3-triazole-5-ylidene type, in which the bpy ligands (bpy = 2,2′-bipyridine) of the archetypical [Ru(bpy)(3)](2+) have been successively...

Descripción completa

Detalles Bibliográficos
Autores principales:	Bens, Tobias, Kübler, Jasmin A., Walter, Robert R. M., Beerhues, Julia, Wenger, Oliver S., Sarkar, Biprajit
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10401885/ https://www.ncbi.nlm.nih.gov/pubmed/37545659 http://dx.doi.org/10.1021/acsorginorgau.3c00005

Ejemplares similares

The transformations of a methylene-bridged bis-triazolium salt: a mesoionic carbene based metallocage and analogues of TCNE and NacNac
por: Stubbe, Jessica, et al.
Publicado: (2021)

Chemistry of Compounds Based on 1,2,3-Triazolylidene-Type Mesoionic Carbenes
por: Maity, Ramananda, et al.
Publicado: (2021)

Mechanistic and Kinetic Investigations of ON/OFF (Photo)Switchable Binding of Carbon Monoxide by Chromium(0), Molybdenum(0) and Tungsten(0) Carbonyl Complexes with a Pyridyl‐Mesoionic Carbene Ligand
por: Boden, Pit J., et al.
Publicado: (2022)

Directed Design of a Au(I) Complex with a Reduced Mesoionic Carbene Radical Ligand: Insights from 1,2,3‐Triazolylidene Selenium Adducts and Extensive Electrochemical Investigations
por: Beerhues, Julia, et al.
Publicado: (2021)

Copper(I) Complexes of Mesoionic Carbene: Structural Characterization and Catalytic Hydrosilylation Reactions
por: Hohloch, Stephan, et al.
Publicado: (2015)

Isomerization Reactions in Anionic Mesoionic Carbene‐Borates and Control of Properties and Reactivities in the Resulting Co(II) Complexes through Agostic Interactions
por: Stubbe, Jessica, et al.
Publicado: (2020)

Palladium(ii)-Acetylacetonato Complexes with Mesoionic Carbenes: Synthesis, Structures and Their Application in the Suzuki-Miyaura Cross Coupling Reaction
por: Hettmanczyk, Lara, et al.
Publicado: (2016)

Strongly Luminescent Pt(IV) Complexes with a Mesoionic N-Heterocyclic Carbene Ligand: Tuning Their Photophysical Properties
por: Vivancos, Ángela, et al.
Publicado: (2021)

Bidentate Donor-Functionalized N-Heterocyclic Carbenes: Valuable Ligands for Ruthenium-Catalyzed Transfer Hydrogenation
por: Ritleng, Vincent, et al.
Publicado: (2022)

Latent ruthenium–indenylidene catalysts bearing a N-heterocyclic carbene and a bidentate picolinate ligand
por: Schmid, Thibault E, et al.
Publicado: (2015)

Stabilization of Boron–Boron Triple Bonds by Mesoionic Carbenes
por: Saha, Ranajit, et al.
Publicado: (2018)

Mesoionic Carbenes in Low- to High-Valent Vanadium Chemistry
por: Neururer, Florian R., et al.
Publicado: (2021)

Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)
por: Seed, John A., et al.
Publicado: (2022)

Cobaltocenylidene: A Mesoionic Metalloceno Carbene, Stabilized in a Gold(III) Complex
por: Vanicek, Stefan, et al.
Publicado: (2018)

The Core Difference between a Mesoionic and a Normal N-Heterocyclic Carbene
por: Barnett, Christopher, et al.
Publicado: (2022)

Synthesis of N,O-bidentate organic difluoroboron complexes and their photophysical studies
por: Guang, Jin, et al.
Publicado: (2023)

Recent Advances in Catalysis Involving Bidentate N-Heterocyclic Carbene Ligands
por: Neshat, Abdollah, et al.
Publicado: (2021)

Nickel‐Catalyzed Intramolecular 1,2‐Aryl Migration of Mesoionic Carbenes (iMICs)
por: Merschel, Arne, et al.
Publicado: (2020)

Tuning the π‐Accepting Properties of Mesoionic Carbenes: A Combined Computational and Experimental Study
por: Dong, Zhaowen, et al.
Publicado: (2021)

Mesoionic Imines (MIIs): Strong Donors and Versatile Ligands for Transition Metals and Main Group Substrates
por: Rudolf, Richard, et al.
Publicado: (2022)

Palladium Mesoionic Carbene Pre-catalyst for General Cross-Coupling Transformations in Deep Eutectic Solvents
por: Marset, Xavier, et al.
Publicado: (2019)

Sydnone Methides—A Forgotten Class of Mesoionic Compounds for the Generation of Anionic N‐Heterocyclic Carbenes
por: Mummel, Sebastian, et al.
Publicado: (2021)

Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin
por: Seed, John A., et al.
Publicado: (2017)

Phosphorescent Tris-cyclometalated Pt(IV) Complexes with Mesoionic N-Heterocyclic Carbene and 2-Arylpyridine Ligands
por: Vivancos, Ángela, et al.
Publicado: (2022)

(Dimesityl)boron Benzodithiophenes: Synthesis, Electrochemical, Photophysical and Theoretical Characterization
por: Menduti, Luigi, et al.
Publicado: (2022)

A Comparison of the Photophysical, Electrochemical and Cytotoxic Properties of meso-(2-, 3- and 4-Pyridyl)-BODIPYs and Their Derivatives
por: Ndung’u, Caroline, et al.
Publicado: (2022)

Photoisomerization and thermal isomerization of ruthenium aqua complexes with chloro-substituted asymmetric bidentate ligands
por: Hirahara, Masanari, et al.
Publicado: (2019)

Theoretical perspective on the electronic structure and photophysical properties for a series of mixed-carbene tris-cyclometalated iridium(iii) complexes
por: Li, Jiawei, et al.
Publicado: (2020)

Spectro Auger
Publicado: (1995)

Ene–yne cross-metathesis with ruthenium carbene catalysts
por: Fischmeister, Cédric, et al.
Publicado: (2011)

Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides
por: Rottschäfer, Dennis, et al.
Publicado: (2019)

Selective Preparation of a Heteroleptic Cyclometallated Ruthenium Complex Capable of Undergoing Photosubstitution of a Bidentate Ligand
por: Cuello‐Garibo, Jordi‐Amat, et al.
Publicado: (2018)

Asymmetric Ruthenium(II) and Osmium(II) Complexes with New Bidentate Polyquinoline Ligands. Synthesis and NMR Characterization
por: Mamo, Antonino, et al.
Publicado: (2010)

Ruthenium Carbene Mediated Metathesis of Oleate-Type Fatty Compounds
por: Marvey, Bassie B., et al.
Publicado: (2008)

A High Molar Extinction Coefficient Mono-Anthracenyl Bipyridyl Heteroleptic Ruthenium(II) Complex: Synthesis, Photophysical and Electrochemical Properties
por: Adeloye, Adewale O., et al.
Publicado: (2011)

A luminescent organic radical with two pyridyl groups: high photostability and dual stimuli-responsive properties, with theoretical analyses of photophysical processes
por: Kimura, Shun, et al.
Publicado: (2018)

A 2,2′-diphosphinotolane as a versatile precursor for the synthesis of P-ylidic mesoionic carbenes via reversible C–P bond formation
por: Wagner, Hannah K., et al.
Publicado: (2021)

Effects of the Bidentate Ligand on the Photophysical Properties, Cellular Uptake, and (Photo)cytotoxicity of Glycoconjugates Based on the [Ru(tpy)(NN)(L)](2+) Scaffold
por: Lameijer, Lucien N., et al.
Publicado: (2018)

Rhodium diamidobenzene complexes: a tale of different substituents on the diamidobenzene ligand
por: Suhr, Simon, et al.
Publicado: (2022)

Luminescent cis-Bis(bipyridyl)ruthenium(II) Complexes with 1,2-Azolylamidino Ligands: Photophysical, Electrochemical Studies, and Photocatalytic Oxidation of Thioethers
por: Cuéllar, Elena, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_p0q7g7vm6aoau1qb6govpvtr21