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Merging Cu(I) and Cu(II) Photocatalysis: Development of a Versatile Oxohalogenation Protocol for the Sequential Cu(II)/Cu(I)-Catalyzed Oxoallylation of Vinylarenes

[Image: see text] A sequential photocatalytic strategy is developed via the merger of Cu(II)/Cu(I)-catalytic cycles for the oxoallylation of vinyl arenes via α-haloketones. The initial Cu(II)-photocatalyzed oxohalogenation exploits ligand-to-metal charge transfer (LMCT) to generate halide radicals f...

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Detalles Bibliográficos
Autores principales:	Mandal, Tirtha, Katta, Narenderreddy, Paps, Hendrik, Reiser, Oliver
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10401886/ https://www.ncbi.nlm.nih.gov/pubmed/37545656 http://dx.doi.org/10.1021/acsorginorgau.3c00011

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