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Revisiting Homochiral versus Heterochiral Interactions through a Long Detective Story of a Useful Azobis-Nitrile and Puzzling Racemate

[Image: see text] This paper documents and reinvestigates the solid-state and crystal structures of 4,4′-azobis-4-cyanopentanoic acid (ACPA), a water-soluble azobis-nitrile of immense utility as a radical initiator in living polymerizations and a labile mechanophore that can be embedded within long...

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Detalles Bibliográficos
Autores principales: García de la Concepción, Juan, Flores-Jiménez, Mirian, Cuccia, Louis A., Light, Mark E., Viedma, Cristóbal, Cintas, Pedro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10402293/
https://www.ncbi.nlm.nih.gov/pubmed/37547876
http://dx.doi.org/10.1021/acs.cgd.3c00372