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Hydrogen-Bonded Matched Ion Pair Gold(I) Catalysis
[Image: see text] The enantioselective reaction of 1,6-enynes with O-, N-, and C-nucleophiles has been developed by matched ion pair gold(I) catalysis in which the chiral gold(I) cation and anion are H-bonded through a urea group. Very high levels of enantiocontrol are achieved (up to >99:1 er) f...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10407850/ https://www.ncbi.nlm.nih.gov/pubmed/37560194 http://dx.doi.org/10.1021/acscatal.3c02638 |