Resolving the Mechanism for H(2)O(2) Decomposition over Zr(IV)-Substituted Lindqvist Tungstate: Evidence of Singlet Oxygen Intermediacy

[Image: see text] The decomposition of hydrogen peroxide (H(2)O(2)) is the main undesired side reaction in catalytic oxidation processes of industrial interest that make use of H(2)O(2) as a terminal oxidant, such as the epoxidation of alkenes. However, the mechanism responsible for this reaction is...

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Detalles Bibliográficos
Autores principales: Maksimchuk, Nataliya V., Puiggalí-Jou, Jordi, Zalomaeva, Olga V., Larionov, Kirill P., Evtushok, Vasilii Yu., Soshnikov, Igor E., Solé-Daura, Albert, Kholdeeva, Oxana A., Poblet, Josep M., Carbó, Jorge J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10407852/
https://www.ncbi.nlm.nih.gov/pubmed/37560188
http://dx.doi.org/10.1021/acscatal.3c02416

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