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Enantiospecific Synthesis of Aniline-Derived Sulfonimidamides

[Image: see text] Reaction of sulfonimidoyl fluorides with anilines and Ca(NTf(2))(2) results in the formation of chiral sulfonimidamides. The reaction proceeds with inversion of the stereocenter at a sulfur atom. Enantiospecificity of the reaction was observed for all studied non-heterocyclic anili...

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Detalles Bibliográficos
Autores principales: Liang, Dong-Dong, Lional, Natassa, Scheepmaker, Bas, Subramaniam, Muthusamy, Li, Guanna, Miloserdov, Fedor M., Zuilhof, Han
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10407922/
https://www.ncbi.nlm.nih.gov/pubmed/37490052
http://dx.doi.org/10.1021/acs.orglett.3c02132