Cargando…

NHC stabilized copper nanoparticles via reduction of a copper NHC complex

The bottom-up synthesis of plasmonic NHC@CuNPs from common starting reagents, via the formation of the synthetically accessible NHC–Cu(i)–Br complex and its reduction by NH(3)·BH(3) is reported. The resulting NHC@CuNPs have been characterized in detail by XPS, TEM and NMR spectroscopy. The stability...

Descripción completa

Detalles Bibliográficos
Autores principales:	Richstein, Robert, Eisen, Constantin, Ge, Lingcong, Chalermnon, Monnaya, Mayer, Florian, Keppler, Bernhard K., Chin, Jia Min, Reithofer, Michael R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10408246/ https://www.ncbi.nlm.nih.gov/pubmed/37477599 http://dx.doi.org/10.1039/d3cc02745g

Ejemplares similares

Hyper crosslinked polymer supported NHC stabilized gold nanoparticles with excellent catalytic performance in flow processes
por: Eisen, Constantin, et al.
Publicado: (2022)

The key role of R–NHC coupling (R = C, H, heteroatom) and M–NHC bond cleavage in the evolution of M/NHC complexes and formation of catalytically active species
por: Chernyshev, Victor M., et al.
Publicado: (2020)

The boron–boron triple bond in NHC→B[triple bond, length as m-dash]B←NHC
por: Holzmann, Nicole, et al.
Publicado: (2015)

Exploring the stability of the NHC–metal bond using thiones as probes
por: Ségaud, Nathalie, et al.
Publicado: (2021)

Stereodivergent propargylic alkylation of enals via cooperative NHC and copper catalysis
por: Wen, Yu-Hua, et al.
Publicado: (2022)

Copper(II) NHC Catalyst for the Formation of Phenol from Arylboronic Acid
por: Sharma, Mitu, et al.
Publicado: (2022)

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes
por: Santoro, Orlando, et al.
Publicado: (2013)

Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis
por: Chernyshev, Victor M., et al.
Publicado: (2018)

Bite-angle bending as a key for understanding group-10 metal reactivity of d(10)-[M(NHC)(2)] complexes with sterically modest NHC ligands
por: Hering, Florian, et al.
Publicado: (2015)

The divergent effects of strong NHC donation in catalysis
por: Lummiss, Justin A. M., et al.
Publicado: (2015)

NHC‐stabilized Parent Arsanylalanes and ‐gallanes
por: Weinhart, Michael A. K., et al.
Publicado: (2020)

Synthesis, structure, and reactions of a copper–sulfido cluster comprised of the parent Cu(2)S unit: {(NHC)Cu}(2)(μ-S)
por: Zhai, Junjie, et al.
Publicado: (2016)

Solvent-free hydroboration of alkynes catalyzed by an NHC–cobalt complex
por: Bołt, Małgorzata, et al.
Publicado: (2022)

Mechanochemical solid state synthesis of copper(I)/NHC complexes with K(3)PO(4)
por: Remy-Speckmann, Ina, et al.
Publicado: (2023)

Oxo-functionalised mesoionic NHC nickel complexes for selective electrocatalytic reduction of CO(2) to formate
por: Bertini, Simone, et al.
Publicado: (2021)

NHC-catalyzed covalent activation of heteroatoms for enantioselective reactions
por: Song, Runjiang, et al.
Publicado: (2021)

Coligand role in the NHC nickel catalyzed C–F bond activation: investigations on the insertion of bis(NHC) nickel into the C–F bond of hexafluorobenzene
por: Kuntze-Fechner, Maximilian W., et al.
Publicado: (2020)

Metathesis Reactions of a NHC‐Stabilized Phosphaborene
por: Koner, Abhishek, et al.
Publicado: (2022)

Insights into the synthesis of NHC-stabilized Au nanoclusters through real-time reaction monitoring
por: Liu, Junliang, et al.
Publicado: (2023)

An NHC‐Mediated Metal‐Free Approach towards an NHC‐Coordinated Endocyclic Disilene
por: Lainer, Thomas, et al.
Publicado: (2022)

Rational synthesis of normal, abnormal and anionic NHC–gallium alkyl complexes: structural, stability and isomerization insights
por: Uzelac, Marina, et al.
Publicado: (2015)

NHC-catalysed benzoin condensation – is it all down to the Breslow intermediate?
por: Rehbein, Julia, et al.
Publicado: (2015)

NHC in Imidazolium Acetate Ionic Liquids: Actual or Potential Presence?
por: Chiarotto, Isabella, et al.
Publicado: (2018)

The reaction of rhenium nitrosyl with a sterically hindered NHC-carbene
por: Grieco, G., et al.
Publicado: (2022)

Bio-inspired NHC-organocatalyzed Stetter reaction in aqueous conditions
por: Debiais, Mégane, et al.
Publicado: (2020)

Anion influences on reactivity and NMR spectroscopic features of NHC precursors
por: Huynh, Han Vinh, et al.
Publicado: (2018)

A bis-NHC–CAAC dimer derived dicationic diradical
por: Nayak, Mithilesh Kumar, et al.
Publicado: (2022)

Possible Synthetic Approaches for Heterobimetallic Complexes by Using nNHC/tzNHC Heteroditopic Carbene Ligands
por: Longhi, Andrea, et al.
Publicado: (2019)

Palladium(0) NHC complexes: a new avenue to highly efficient phosphorescence
por: Henwood, Adam F., et al.
Publicado: (2015)

NHC‐Stabilized Iridium Nanoparticles as Catalysts in Hydrogen Isotope Exchange Reactions of Anilines
por: Valero, Mégane, et al.
Publicado: (2020)

Modulating NHC catalysis with fluorine
por: Rey, Yannick P, et al.
Publicado: (2013)

Highly diastereoselective preparation of chiral NHC-boranes stereogenic at the boron atom
por: Aupic, Clara, et al.
Publicado: (2019)

Mechanism and stereoselectivity in NHC-catalyzed β-functionalization of saturated carboxylic ester
por: Li, Yan, et al.
Publicado: (2019)

Photoinduced successive oxidative ring-opening and borylation of indolizines with NHC–boranes
por: Zheng, Huitao, et al.
Publicado: (2021)

Formation of a nonanuclear copper(II) cluster with 3,5-dimethylpyrazolate starting from an NHC complex of copper(I) chloride
por: Dodds, Christopher A., et al.
Publicado: (2020)

Energy transfer (EnT) photocatalysis enabled by gold-N-heterocyclic carbene (NHC) complexes
por: Martynova, Ekaterina A., et al.
Publicado: (2022)

Biological Activities of Ruthenium NHC Complexes: An Update
por: Catalano, Alessia, et al.
Publicado: (2023)

Ag–NHC Complexes in the π-Activation of Alkynes
por: Yang, Shiyi, et al.
Publicado: (2023)

Moving from Classical Ru-NHC to Neutral or Charged Rh-NHC Based Catalysts in Olefin Metathesis
por: Poater, Albert
Publicado: (2016)

Accelerating the insertion reactions of (NHC)Cu–H via remote ligand functionalization
por: Speelman, Amy L., et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_ui82r87dlrns07197ikducrknn