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Sulfur-mediated chalcogen versus hydrogen bonds in proteins: a see-saw effect in the conformational space
Divalent sulfur (S) forms a chalcogen bond (Ch-bond) via its σ-holes and a hydrogen bond (H-bond) via its lone pairs. The relevance of these interactions and their interplay for protein structure and function is unclear. Based on the analyses of the crystal structures of small organic/organometallic...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Cambridge University Press
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10411326/ https://www.ncbi.nlm.nih.gov/pubmed/37564297 http://dx.doi.org/10.1017/qrd.2023.3 |