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Sulfur-mediated chalcogen versus hydrogen bonds in proteins: a see-saw effect in the conformational space

Divalent sulfur (S) forms a chalcogen bond (Ch-bond) via its σ-holes and a hydrogen bond (H-bond) via its lone pairs. The relevance of these interactions and their interplay for protein structure and function is unclear. Based on the analyses of the crystal structures of small organic/organometallic...

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Detalles Bibliográficos
Autores principales: Adhav, Vishal Annasaheb, Shelke, Sanket Satish, Balanarayan, Pananghat, Saikrishnan, Kayarat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Cambridge University Press 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10411326/
https://www.ncbi.nlm.nih.gov/pubmed/37564297
http://dx.doi.org/10.1017/qrd.2023.3