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Cationic tetranuclear macrocyclic CaCo(3) complexes as highly active catalysts for alternating copolymerization of propylene oxide and carbon dioxide

We found that a cationic hetero tetranuclear complex including a calcium and three cobalts exhibited high catalytic activity toward alternating copolymerization of propylene oxide (PO) and carbon dioxide (CO(2)). The tertiary anilinium salt [PhNMe(2)H][B(C(6)F(5))(4)] was the best additive to genera...

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Detalles Bibliográficos
Autores principales:	Nagae, Haruki, Matsushiro, Saki, Okuda, Jun, Mashima, Kazushi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10411860/ https://www.ncbi.nlm.nih.gov/pubmed/37564411 http://dx.doi.org/10.1039/d3sc00974b

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