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Insights into the protonation state and spin structure for the g = 2 multiline electron paramagnetic resonance signal of the oxygen-evolving complex
In photosystem II (PSII), one-electron oxidation of the most stable oxidation state of the Mn(4)CaO(5) cluster (S(1)) leads to formation of two distinct states, the open-cubane S(2) conformation [Mn1(III)Mn2(IV)Mn3(IV)Mn4(IV)] with low spin and the closed-cubane S(2) conformation [Mn1(IV)Mn2(IV)Mn3(...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Oxford University Press
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10411963/ https://www.ncbi.nlm.nih.gov/pubmed/37564363 http://dx.doi.org/10.1093/pnasnexus/pgad244 |