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Diastereo- and atroposelective synthesis of N-arylpyrroles enabled by light-induced phosphoric acid catalysis

The C−N axially chiral N-arylpyrrole motifs are privileged scaffolds in numerous biologically active molecules and natural products, as well as in chiral ligands/catalysts. Asymmetric synthesis of N-arylpyrroles, however, is still challenging, and the simultaneous creation of contiguous C−N axial an...

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Detalles Bibliográficos
Autores principales: Dai, Lei, Zhou, Xueting, Guo, Jiami, Dai, Xuan, Huang, Qingqin, Lu, Yixin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10412603/
https://www.ncbi.nlm.nih.gov/pubmed/37558716
http://dx.doi.org/10.1038/s41467-023-40491-8