Functionalization of polyethylene with hydrolytically-stable ester groups

Low-density (LD) and high-density polyethylene (HDPE), recycled or not, incorporates up to 7 wt% of ester groups after reacting either with ethyl diazoacetate (EDA) under catalytic and solvent free-reaction conditions, or with maleic anhydride (MA) and acrylates (AC) under catalytic radical conditio...

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Detalles Bibliográficos
Autores principales: Hervàs-Arnandis, Susi, Palomar-de Lucas, Brenda, Bilanin, Cristina, Mingueza-Verdejo, Paloma, Viciano, Mónica, Oliver-Meseguer, Judit, Leyva-Pérez, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10413336/
https://www.ncbi.nlm.nih.gov/pubmed/37577098
http://dx.doi.org/10.1039/d3ra05024f
Descripción
Sumario:Low-density (LD) and high-density polyethylene (HDPE), recycled or not, incorporates up to 7 wt% of ester groups after reacting either with ethyl diazoacetate (EDA) under catalytic and solvent free-reaction conditions, or with maleic anhydride (MA) and acrylates (AC) under catalytic radical conditions. The resulting upcycled polyethylene esters are hydrolytically stable at extreme pH (0–14) and can be further transformed into carboxylic acids, carboxylates, other esters and amides.

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