Functionalization of polyethylene with hydrolytically-stable ester groups

Low-density (LD) and high-density polyethylene (HDPE), recycled or not, incorporates up to 7 wt% of ester groups after reacting either with ethyl diazoacetate (EDA) under catalytic and solvent free-reaction conditions, or with maleic anhydride (MA) and acrylates (AC) under catalytic radical conditio...

Descripción completa

Detalles Bibliográficos
Autores principales: Hervàs-Arnandis, Susi, Palomar-de Lucas, Brenda, Bilanin, Cristina, Mingueza-Verdejo, Paloma, Viciano, Mónica, Oliver-Meseguer, Judit, Leyva-Pérez, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10413336/
https://www.ncbi.nlm.nih.gov/pubmed/37577098
http://dx.doi.org/10.1039/d3ra05024f
_version_ 1785087107548577792
author Hervàs-Arnandis, Susi
Palomar-de Lucas, Brenda
Bilanin, Cristina
Mingueza-Verdejo, Paloma
Viciano, Mónica
Oliver-Meseguer, Judit
Leyva-Pérez, Antonio
author_facet Hervàs-Arnandis, Susi
Palomar-de Lucas, Brenda
Bilanin, Cristina
Mingueza-Verdejo, Paloma
Viciano, Mónica
Oliver-Meseguer, Judit
Leyva-Pérez, Antonio
author_sort Hervàs-Arnandis, Susi
collection PubMed
description Low-density (LD) and high-density polyethylene (HDPE), recycled or not, incorporates up to 7 wt% of ester groups after reacting either with ethyl diazoacetate (EDA) under catalytic and solvent free-reaction conditions, or with maleic anhydride (MA) and acrylates (AC) under catalytic radical conditions. The resulting upcycled polyethylene esters are hydrolytically stable at extreme pH (0–14) and can be further transformed into carboxylic acids, carboxylates, other esters and amides.
format Online
Article
Text
id pubmed-10413336
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-104133362023-08-11 Functionalization of polyethylene with hydrolytically-stable ester groups Hervàs-Arnandis, Susi Palomar-de Lucas, Brenda Bilanin, Cristina Mingueza-Verdejo, Paloma Viciano, Mónica Oliver-Meseguer, Judit Leyva-Pérez, Antonio RSC Adv Chemistry Low-density (LD) and high-density polyethylene (HDPE), recycled or not, incorporates up to 7 wt% of ester groups after reacting either with ethyl diazoacetate (EDA) under catalytic and solvent free-reaction conditions, or with maleic anhydride (MA) and acrylates (AC) under catalytic radical conditions. The resulting upcycled polyethylene esters are hydrolytically stable at extreme pH (0–14) and can be further transformed into carboxylic acids, carboxylates, other esters and amides. The Royal Society of Chemistry 2023-08-10 /pmc/articles/PMC10413336/ /pubmed/37577098 http://dx.doi.org/10.1039/d3ra05024f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Hervàs-Arnandis, Susi
Palomar-de Lucas, Brenda
Bilanin, Cristina
Mingueza-Verdejo, Paloma
Viciano, Mónica
Oliver-Meseguer, Judit
Leyva-Pérez, Antonio
Functionalization of polyethylene with hydrolytically-stable ester groups
title Functionalization of polyethylene with hydrolytically-stable ester groups
title_full Functionalization of polyethylene with hydrolytically-stable ester groups
title_fullStr Functionalization of polyethylene with hydrolytically-stable ester groups
title_full_unstemmed Functionalization of polyethylene with hydrolytically-stable ester groups
title_short Functionalization of polyethylene with hydrolytically-stable ester groups
title_sort functionalization of polyethylene with hydrolytically-stable ester groups
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10413336/
https://www.ncbi.nlm.nih.gov/pubmed/37577098
http://dx.doi.org/10.1039/d3ra05024f
work_keys_str_mv AT hervasarnandissusi functionalizationofpolyethylenewithhydrolyticallystableestergroups
AT palomardelucasbrenda functionalizationofpolyethylenewithhydrolyticallystableestergroups
AT bilanincristina functionalizationofpolyethylenewithhydrolyticallystableestergroups
AT minguezaverdejopaloma functionalizationofpolyethylenewithhydrolyticallystableestergroups
AT vicianomonica functionalizationofpolyethylenewithhydrolyticallystableestergroups
AT olivermeseguerjudit functionalizationofpolyethylenewithhydrolyticallystableestergroups
AT leyvaperezantonio functionalizationofpolyethylenewithhydrolyticallystableestergroups

Ejemplares similares