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Yield-stress transition in suspensions of deformable droplets

Yield-stress materials, which require a sufficiently large forcing to flow, are currently ill-understood theoretically. To gain insight into their yielding transition, we study numerically the rheology of a suspension of deformable droplets in 2D. We show that the suspension displays yield-stress be...

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Autores principales: Negro, Giuseppe, Carenza, Livio Nicola, Gonnella, Giuseppe, Mackay, Fraser, Morozov, Alexander, Marenduzzo, Davide
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10413676/
https://www.ncbi.nlm.nih.gov/pubmed/37256946
http://dx.doi.org/10.1126/sciadv.adf8106
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author Negro, Giuseppe
Carenza, Livio Nicola
Gonnella, Giuseppe
Mackay, Fraser
Morozov, Alexander
Marenduzzo, Davide
author_facet Negro, Giuseppe
Carenza, Livio Nicola
Gonnella, Giuseppe
Mackay, Fraser
Morozov, Alexander
Marenduzzo, Davide
author_sort Negro, Giuseppe
collection PubMed
description Yield-stress materials, which require a sufficiently large forcing to flow, are currently ill-understood theoretically. To gain insight into their yielding transition, we study numerically the rheology of a suspension of deformable droplets in 2D. We show that the suspension displays yield-stress behavior, with droplets remaining motionless below a critical body-force. In this phase, droplets jam to form an amorphous structure, whereas they order in the flowing phase. Yielding is linked to a percolation transition in the contacts of droplet-droplet overlaps and requires strict conservation of the droplet area to exist. Close to the transition, we find strong oscillations in the droplet motion that resemble those found experimentally in confined colloidal glasses. We show that even when droplets are static, the underlying solvent moves by permeation so that the viscosity of the composite system is never truly infinite, and its value ceases to be a bulk material property of the system.
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spelling pubmed-104136762023-08-11 Yield-stress transition in suspensions of deformable droplets Negro, Giuseppe Carenza, Livio Nicola Gonnella, Giuseppe Mackay, Fraser Morozov, Alexander Marenduzzo, Davide Sci Adv Physical and Materials Sciences Yield-stress materials, which require a sufficiently large forcing to flow, are currently ill-understood theoretically. To gain insight into their yielding transition, we study numerically the rheology of a suspension of deformable droplets in 2D. We show that the suspension displays yield-stress behavior, with droplets remaining motionless below a critical body-force. In this phase, droplets jam to form an amorphous structure, whereas they order in the flowing phase. Yielding is linked to a percolation transition in the contacts of droplet-droplet overlaps and requires strict conservation of the droplet area to exist. Close to the transition, we find strong oscillations in the droplet motion that resemble those found experimentally in confined colloidal glasses. We show that even when droplets are static, the underlying solvent moves by permeation so that the viscosity of the composite system is never truly infinite, and its value ceases to be a bulk material property of the system. American Association for the Advancement of Science 2023-05-31 /pmc/articles/PMC10413676/ /pubmed/37256946 http://dx.doi.org/10.1126/sciadv.adf8106 Text en Copyright © 2023 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution License 4.0 (CC BY). https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution license (https://creativecommons.org/licenses/by/4.0/) , which permits which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Physical and Materials Sciences
Negro, Giuseppe
Carenza, Livio Nicola
Gonnella, Giuseppe
Mackay, Fraser
Morozov, Alexander
Marenduzzo, Davide
Yield-stress transition in suspensions of deformable droplets
title Yield-stress transition in suspensions of deformable droplets
title_full Yield-stress transition in suspensions of deformable droplets
title_fullStr Yield-stress transition in suspensions of deformable droplets
title_full_unstemmed Yield-stress transition in suspensions of deformable droplets
title_short Yield-stress transition in suspensions of deformable droplets
title_sort yield-stress transition in suspensions of deformable droplets
topic Physical and Materials Sciences
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10413676/
https://www.ncbi.nlm.nih.gov/pubmed/37256946
http://dx.doi.org/10.1126/sciadv.adf8106
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