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Cu(triNHC)-catalyzed polymerization of glycidol to produce ultralow-branched polyglycerol

We have successfully synthesized a novel form of polyglycerol with an unprecedentedly low degree of branching (DB = 0.08–0.18), eliminating the need for glycidol protection. Leveraging the remarkable efficiency and selectivity of our Cu(triNHC) catalyst, comprising copper(i) ions and NHC ligands, we...

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Detalles Bibliográficos
Autores principales: Sung, Kihyuk, Baek, Jinsu, Choi, Soonyoung, Kim, Byeong-Su, Lee, Sang-Ho, Lee, In-Hwan, Jang, Hye-Young
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10415747/
https://www.ncbi.nlm.nih.gov/pubmed/37577101
http://dx.doi.org/10.1039/d3ra04422j