Facile Functionalization of Ambipolar, Nitrogen-Doped PAHs toward Highly Efficient TADF OLED Emitters

[Image: see text] Despite promising optoelectronic features of N-doped polycyclic aromatic hydrocarbons (PAHs), their use as functional materials remains underdeveloped due to their limited post-functionalization. Facing this challenge, a novel design of N-doped PAHs with D–A–D electronic structure for thermally activated delayed fluorescence (TADF) emitters was performed. Implementing a set of auxiliary donors at the meta position of the protruding phenyl ring of quinoxaline triggers an increase in the charge-transfer property simultaneously decreasing the delayed fluorescence lifetime. This, in turn, contributes to a narrow (0.04–0.28 eV) singlet–triplet exchange energy split (ΔE(ST)) and promotes a reverse intersystem crossing transition that is pivotal for an efficient TADF process. Boosting the electron-donating ability of our N-PAH scaffold leads to excellent photoluminescence quantum yield that was found in a solid-state matrix up to 96% (for phenoxazine-substituted derivatives, under air) with yellow or orange-red emission, depending on the specific compound. Organic light-emitting diodes (OLEDs) utilizing six, (D–A)–D, N-PAH emitters demonstrate a significant throughput with a maximum external quantum efficiency of 21.9% which is accompanied by remarkable luminance values which were found for all investigated devices in the range of 20,000–30,100 cd/m(2) which is the highest reported to date for N-doped PAHs investigated in the OLED domain.