Preparation and Testing of a Palladium-Decorated Nitrogen-Doped Carbon Foam Catalyst for the Hydrogenation of Benzophenone

Catalytic activity of a palladium catalyst with a porous carbon support was prepared and tested for benzophenone hydrogenation. The selectivity and yields toward the two possible reaction products (benzhydrol and diphenylmethane) can be directed by the applied solvent. It was found that in isopropan...

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Autores principales: Prekob, Ádám, Hajdu, Viktória, Fejes, Zsolt, Kristály, Ferenc, Viskolcz, Béla, Vanyorek, László
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10418342/
https://www.ncbi.nlm.nih.gov/pubmed/37569588
http://dx.doi.org/10.3390/ijms241512211
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author Prekob, Ádám
Hajdu, Viktória
Fejes, Zsolt
Kristály, Ferenc
Viskolcz, Béla
Vanyorek, László
author_facet Prekob, Ádám
Hajdu, Viktória
Fejes, Zsolt
Kristály, Ferenc
Viskolcz, Béla
Vanyorek, László
author_sort Prekob, Ádám
collection PubMed
description Catalytic activity of a palladium catalyst with a porous carbon support was prepared and tested for benzophenone hydrogenation. The selectivity and yields toward the two possible reaction products (benzhydrol and diphenylmethane) can be directed by the applied solvent. It was found that in isopropanol, the prepared support was selective towards diphenylmethane with high conversion (99% selectivity and 99% benzophenone conversion on 323 K after 240 min). This selectivity might be explained by the presence of the incorporated structural nitrogens in the support.
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spelling pubmed-104183422023-08-12 Preparation and Testing of a Palladium-Decorated Nitrogen-Doped Carbon Foam Catalyst for the Hydrogenation of Benzophenone Prekob, Ádám Hajdu, Viktória Fejes, Zsolt Kristály, Ferenc Viskolcz, Béla Vanyorek, László Int J Mol Sci Communication Catalytic activity of a palladium catalyst with a porous carbon support was prepared and tested for benzophenone hydrogenation. The selectivity and yields toward the two possible reaction products (benzhydrol and diphenylmethane) can be directed by the applied solvent. It was found that in isopropanol, the prepared support was selective towards diphenylmethane with high conversion (99% selectivity and 99% benzophenone conversion on 323 K after 240 min). This selectivity might be explained by the presence of the incorporated structural nitrogens in the support. MDPI 2023-07-30 /pmc/articles/PMC10418342/ /pubmed/37569588 http://dx.doi.org/10.3390/ijms241512211 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Prekob, Ádám
Hajdu, Viktória
Fejes, Zsolt
Kristály, Ferenc
Viskolcz, Béla
Vanyorek, László
Preparation and Testing of a Palladium-Decorated Nitrogen-Doped Carbon Foam Catalyst for the Hydrogenation of Benzophenone
title Preparation and Testing of a Palladium-Decorated Nitrogen-Doped Carbon Foam Catalyst for the Hydrogenation of Benzophenone
title_full Preparation and Testing of a Palladium-Decorated Nitrogen-Doped Carbon Foam Catalyst for the Hydrogenation of Benzophenone
title_fullStr Preparation and Testing of a Palladium-Decorated Nitrogen-Doped Carbon Foam Catalyst for the Hydrogenation of Benzophenone
title_full_unstemmed Preparation and Testing of a Palladium-Decorated Nitrogen-Doped Carbon Foam Catalyst for the Hydrogenation of Benzophenone
title_short Preparation and Testing of a Palladium-Decorated Nitrogen-Doped Carbon Foam Catalyst for the Hydrogenation of Benzophenone
title_sort preparation and testing of a palladium-decorated nitrogen-doped carbon foam catalyst for the hydrogenation of benzophenone
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10418342/
https://www.ncbi.nlm.nih.gov/pubmed/37569588
http://dx.doi.org/10.3390/ijms241512211
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