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The Preparation, Characterization, and Pressure-Influenced Dihydrogen Interactions of Tetramethylphosphonium Borohydride
Tetramethylphosphonium borohydride was synthesized via an ion metathesis reaction in a weakly-coordinating aprotic environment. [(CH(3))(4)P]BH(4), in contrast to related [(CH(3))(4)N](+) compounds which tend to crystallize in a tetragonal system, adopts the distorted wurtzite structure (P6(3)mc), r...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10420206/ https://www.ncbi.nlm.nih.gov/pubmed/37570038 http://dx.doi.org/10.3390/ma16155334 |