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Ru and Se Co-Doped Cobalt Hydroxide Electrocatalyst for Efficient Hydrogen Evolution Reactions

The development of efficient electrocatalysts for hydrogen evolution reactions is an extremely important area for the development of green and clean energy. In this work, a precursor material was successfully prepared via electrodeposition of two doping elements to construct a co-doped cobalt hydrox...

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Autores principales: Peng, Weizhong, Yuan, Yuting, Huang, Chao, Wu, Yulong, Xiao, Zhaohui, Zhan, Guanghui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10420253/
https://www.ncbi.nlm.nih.gov/pubmed/37570706
http://dx.doi.org/10.3390/molecules28155736
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author Peng, Weizhong
Yuan, Yuting
Huang, Chao
Wu, Yulong
Xiao, Zhaohui
Zhan, Guanghui
author_facet Peng, Weizhong
Yuan, Yuting
Huang, Chao
Wu, Yulong
Xiao, Zhaohui
Zhan, Guanghui
author_sort Peng, Weizhong
collection PubMed
description The development of efficient electrocatalysts for hydrogen evolution reactions is an extremely important area for the development of green and clean energy. In this work, a precursor material was successfully prepared via electrodeposition of two doping elements to construct a co-doped cobalt hydroxide electrocatalyst (Ru-Co(OH)(2)-Se). This approach was demonstrated to be an effective way to improve the performance of the hydrogen evolution reaction (HER). The experimental results show that the material exhibited a smaller impedance value and a larger electrochemically active surface area. In the HER process, the overpotential was only 109 mV at a current density of 10 mA/cm(2). In addition, the doping of selenium and ruthenium effectively prevented the corrosion of the catalysts, with the (Ru-Co(OH)(2)-Se) material showing no significant reduction in the catalytic performance after 50 h. This synergistic approach through elemental co-doping demonstrated good results in the HER process.
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spelling pubmed-104202532023-08-12 Ru and Se Co-Doped Cobalt Hydroxide Electrocatalyst for Efficient Hydrogen Evolution Reactions Peng, Weizhong Yuan, Yuting Huang, Chao Wu, Yulong Xiao, Zhaohui Zhan, Guanghui Molecules Article The development of efficient electrocatalysts for hydrogen evolution reactions is an extremely important area for the development of green and clean energy. In this work, a precursor material was successfully prepared via electrodeposition of two doping elements to construct a co-doped cobalt hydroxide electrocatalyst (Ru-Co(OH)(2)-Se). This approach was demonstrated to be an effective way to improve the performance of the hydrogen evolution reaction (HER). The experimental results show that the material exhibited a smaller impedance value and a larger electrochemically active surface area. In the HER process, the overpotential was only 109 mV at a current density of 10 mA/cm(2). In addition, the doping of selenium and ruthenium effectively prevented the corrosion of the catalysts, with the (Ru-Co(OH)(2)-Se) material showing no significant reduction in the catalytic performance after 50 h. This synergistic approach through elemental co-doping demonstrated good results in the HER process. MDPI 2023-07-28 /pmc/articles/PMC10420253/ /pubmed/37570706 http://dx.doi.org/10.3390/molecules28155736 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Peng, Weizhong
Yuan, Yuting
Huang, Chao
Wu, Yulong
Xiao, Zhaohui
Zhan, Guanghui
Ru and Se Co-Doped Cobalt Hydroxide Electrocatalyst for Efficient Hydrogen Evolution Reactions
title Ru and Se Co-Doped Cobalt Hydroxide Electrocatalyst for Efficient Hydrogen Evolution Reactions
title_full Ru and Se Co-Doped Cobalt Hydroxide Electrocatalyst for Efficient Hydrogen Evolution Reactions
title_fullStr Ru and Se Co-Doped Cobalt Hydroxide Electrocatalyst for Efficient Hydrogen Evolution Reactions
title_full_unstemmed Ru and Se Co-Doped Cobalt Hydroxide Electrocatalyst for Efficient Hydrogen Evolution Reactions
title_short Ru and Se Co-Doped Cobalt Hydroxide Electrocatalyst for Efficient Hydrogen Evolution Reactions
title_sort ru and se co-doped cobalt hydroxide electrocatalyst for efficient hydrogen evolution reactions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10420253/
https://www.ncbi.nlm.nih.gov/pubmed/37570706
http://dx.doi.org/10.3390/molecules28155736
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