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Traditional vs. Energetic and Perchlorate vs. “Green”: A Comparative Study of the Choice of Binders and Oxidising Agents
The aim of this article is to compare rocket propellants containing a traditional binder (hydroxyl-terminated polybutadiene) and an energetic binder (glycidyl azide polymer), as well as a perchlorate oxidising agent and a “green” one, i.e., ammonium perchlorate and phase-stabilised ammonium nitrate....
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10420929/ https://www.ncbi.nlm.nih.gov/pubmed/37570756 http://dx.doi.org/10.3390/molecules28155787 |
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author | Lysien, Kinga Waśkiewicz, Sylwia Stolarczyk, Agnieszka Mielańczyk, Anna Zakusylo, Roman Jarosz, Tomasz |
author_facet | Lysien, Kinga Waśkiewicz, Sylwia Stolarczyk, Agnieszka Mielańczyk, Anna Zakusylo, Roman Jarosz, Tomasz |
author_sort | Lysien, Kinga |
collection | PubMed |
description | The aim of this article is to compare rocket propellants containing a traditional binder (hydroxyl-terminated polybutadiene) and an energetic binder (glycidyl azide polymer), as well as a perchlorate oxidising agent and a “green” one, i.e., ammonium perchlorate and phase-stabilised ammonium nitrate. We have outlined the effects of individual substances on the sensitivity parameters and decomposition temperature of the produced solid propellants. The linear combustion velocity was determined using electrical methods. Heats of combustion for the propellant samples and the thermal decomposition features of the utilised binders were investigated via differential scanning calorimetry (DSC). Activation energy values for the energetic decomposition of the propellants were determined via the Kissinger method, based on DSC measurements at varied heating rates. |
format | Online Article Text |
id | pubmed-10420929 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-104209292023-08-12 Traditional vs. Energetic and Perchlorate vs. “Green”: A Comparative Study of the Choice of Binders and Oxidising Agents Lysien, Kinga Waśkiewicz, Sylwia Stolarczyk, Agnieszka Mielańczyk, Anna Zakusylo, Roman Jarosz, Tomasz Molecules Article The aim of this article is to compare rocket propellants containing a traditional binder (hydroxyl-terminated polybutadiene) and an energetic binder (glycidyl azide polymer), as well as a perchlorate oxidising agent and a “green” one, i.e., ammonium perchlorate and phase-stabilised ammonium nitrate. We have outlined the effects of individual substances on the sensitivity parameters and decomposition temperature of the produced solid propellants. The linear combustion velocity was determined using electrical methods. Heats of combustion for the propellant samples and the thermal decomposition features of the utilised binders were investigated via differential scanning calorimetry (DSC). Activation energy values for the energetic decomposition of the propellants were determined via the Kissinger method, based on DSC measurements at varied heating rates. MDPI 2023-07-31 /pmc/articles/PMC10420929/ /pubmed/37570756 http://dx.doi.org/10.3390/molecules28155787 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Lysien, Kinga Waśkiewicz, Sylwia Stolarczyk, Agnieszka Mielańczyk, Anna Zakusylo, Roman Jarosz, Tomasz Traditional vs. Energetic and Perchlorate vs. “Green”: A Comparative Study of the Choice of Binders and Oxidising Agents |
title | Traditional vs. Energetic and Perchlorate vs. “Green”: A Comparative Study of the Choice of Binders and Oxidising Agents |
title_full | Traditional vs. Energetic and Perchlorate vs. “Green”: A Comparative Study of the Choice of Binders and Oxidising Agents |
title_fullStr | Traditional vs. Energetic and Perchlorate vs. “Green”: A Comparative Study of the Choice of Binders and Oxidising Agents |
title_full_unstemmed | Traditional vs. Energetic and Perchlorate vs. “Green”: A Comparative Study of the Choice of Binders and Oxidising Agents |
title_short | Traditional vs. Energetic and Perchlorate vs. “Green”: A Comparative Study of the Choice of Binders and Oxidising Agents |
title_sort | traditional vs. energetic and perchlorate vs. “green”: a comparative study of the choice of binders and oxidising agents |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10420929/ https://www.ncbi.nlm.nih.gov/pubmed/37570756 http://dx.doi.org/10.3390/molecules28155787 |
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