Synthesis and Characterization of Bulky Substituted Hemihexaphyrazines Bearing 2,6-Diisopropylphenoxy Groups

New substituted [30]trithiadodecaazahexaphyrines (hemihexaphyrazines) were synthesized by a crossover condensation of 2,5-diamino-1,3,4-thiadiazole with 4-chloro-5-(2,6-diisopropylphenoxy)- or 4,5-bis-(2,6-diisopropylphenoxy)phthalonitriles. The compounds were characterized by (1)H-, (13)C-NMR, incl...

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Autores principales: Ivanov, Evgenii N., Almeida-Marrero, Verónica, Koifman, Oskar I., Aleksandriiskii, Viktor V., Torres, Tomas, Islyaikin, Mikhail K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10421089/
https://www.ncbi.nlm.nih.gov/pubmed/37570710
http://dx.doi.org/10.3390/molecules28155740
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author Ivanov, Evgenii N.
Almeida-Marrero, Verónica
Koifman, Oskar I.
Aleksandriiskii, Viktor V.
Torres, Tomas
Islyaikin, Mikhail K.
author_facet Ivanov, Evgenii N.
Almeida-Marrero, Verónica
Koifman, Oskar I.
Aleksandriiskii, Viktor V.
Torres, Tomas
Islyaikin, Mikhail K.
author_sort Ivanov, Evgenii N.
collection PubMed
description New substituted [30]trithiadodecaazahexaphyrines (hemihexaphyrazines) were synthesized by a crossover condensation of 2,5-diamino-1,3,4-thiadiazole with 4-chloro-5-(2,6-diisopropylphenoxy)- or 4,5-bis-(2,6-diisopropylphenoxy)phthalonitriles. The compounds were characterized by (1)H-, (13)C-NMR, including COSY, HMBC, and HSQC spectroscopy, MALDI TOF spectrometry, elemental analysis, IR and UV-Vis absorbance and fluorescence techniques.
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spelling pubmed-104210892023-08-12 Synthesis and Characterization of Bulky Substituted Hemihexaphyrazines Bearing 2,6-Diisopropylphenoxy Groups Ivanov, Evgenii N. Almeida-Marrero, Verónica Koifman, Oskar I. Aleksandriiskii, Viktor V. Torres, Tomas Islyaikin, Mikhail K. Molecules Article New substituted [30]trithiadodecaazahexaphyrines (hemihexaphyrazines) were synthesized by a crossover condensation of 2,5-diamino-1,3,4-thiadiazole with 4-chloro-5-(2,6-diisopropylphenoxy)- or 4,5-bis-(2,6-diisopropylphenoxy)phthalonitriles. The compounds were characterized by (1)H-, (13)C-NMR, including COSY, HMBC, and HSQC spectroscopy, MALDI TOF spectrometry, elemental analysis, IR and UV-Vis absorbance and fluorescence techniques. MDPI 2023-07-29 /pmc/articles/PMC10421089/ /pubmed/37570710 http://dx.doi.org/10.3390/molecules28155740 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ivanov, Evgenii N.
Almeida-Marrero, Verónica
Koifman, Oskar I.
Aleksandriiskii, Viktor V.
Torres, Tomas
Islyaikin, Mikhail K.
Synthesis and Characterization of Bulky Substituted Hemihexaphyrazines Bearing 2,6-Diisopropylphenoxy Groups
title Synthesis and Characterization of Bulky Substituted Hemihexaphyrazines Bearing 2,6-Diisopropylphenoxy Groups
title_full Synthesis and Characterization of Bulky Substituted Hemihexaphyrazines Bearing 2,6-Diisopropylphenoxy Groups
title_fullStr Synthesis and Characterization of Bulky Substituted Hemihexaphyrazines Bearing 2,6-Diisopropylphenoxy Groups
title_full_unstemmed Synthesis and Characterization of Bulky Substituted Hemihexaphyrazines Bearing 2,6-Diisopropylphenoxy Groups
title_short Synthesis and Characterization of Bulky Substituted Hemihexaphyrazines Bearing 2,6-Diisopropylphenoxy Groups
title_sort synthesis and characterization of bulky substituted hemihexaphyrazines bearing 2,6-diisopropylphenoxy groups
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10421089/
https://www.ncbi.nlm.nih.gov/pubmed/37570710
http://dx.doi.org/10.3390/molecules28155740
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