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Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture
Sustainable development goal 12 advocates the production and consumption of green and sustainable commodities. As such, pressure is mounting on the oil and gas industries for a paradigm shift. This work explores the potential of aspartame (a derivative of aspartic acid and phenylalanine) based formu...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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Nature Publishing Group UK
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10421942/ https://www.ncbi.nlm.nih.gov/pubmed/37567963 http://dx.doi.org/10.1038/s41598-023-40354-8 |
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author | Solomon, Moses M. |
author_facet | Solomon, Moses M. |
author_sort | Solomon, Moses M. |
collection | PubMed |
description | Sustainable development goal 12 advocates the production and consumption of green and sustainable commodities. As such, pressure is mounting on the oil and gas industries for a paradigm shift. This work explores the potential of aspartame (a derivative of aspartic acid and phenylalanine) based formulation as a green inhibitor. The inhibiting effect of aspartame alone and in combination with potassium iodide (KI) or sodium dodecyl sulphate (SDS) or both on T95 steel in 15 wt% HCl solution at 60–90 °C is investigated using weight loss, electrochemical, and surface analysis techniques. The results show severe metal corrosion especially at 90 °C with a corrosion rate (v) of 186.37 mm/y. Aspartame inhibits corrosion and its inhibition efficiency (η) increases with an increase in temperature. At 6.80 mM, η of 86% is obtained at 90 °C. The addition of SDS to aspartame produces an antagonistic effect. A KI-aspartame mixture produces an antagonistic effect at 60 °C and 70 °C but a synergistic effect at 80 °C and 90 °C. There is a strong synergy when aspartame (6.80 mM), KI (1 mM), and SDS (1 mM) are mixed especially at higher temperatures. The mixture reduces v from 186.37 to 14.35 mm/y, protecting the metal surface by 92% at 90 °C. The mixture can be considered an acidizing corrosion inhibitor. |
format | Online Article Text |
id | pubmed-10421942 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-104219422023-08-13 Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture Solomon, Moses M. Sci Rep Article Sustainable development goal 12 advocates the production and consumption of green and sustainable commodities. As such, pressure is mounting on the oil and gas industries for a paradigm shift. This work explores the potential of aspartame (a derivative of aspartic acid and phenylalanine) based formulation as a green inhibitor. The inhibiting effect of aspartame alone and in combination with potassium iodide (KI) or sodium dodecyl sulphate (SDS) or both on T95 steel in 15 wt% HCl solution at 60–90 °C is investigated using weight loss, electrochemical, and surface analysis techniques. The results show severe metal corrosion especially at 90 °C with a corrosion rate (v) of 186.37 mm/y. Aspartame inhibits corrosion and its inhibition efficiency (η) increases with an increase in temperature. At 6.80 mM, η of 86% is obtained at 90 °C. The addition of SDS to aspartame produces an antagonistic effect. A KI-aspartame mixture produces an antagonistic effect at 60 °C and 70 °C but a synergistic effect at 80 °C and 90 °C. There is a strong synergy when aspartame (6.80 mM), KI (1 mM), and SDS (1 mM) are mixed especially at higher temperatures. The mixture reduces v from 186.37 to 14.35 mm/y, protecting the metal surface by 92% at 90 °C. The mixture can be considered an acidizing corrosion inhibitor. Nature Publishing Group UK 2023-08-11 /pmc/articles/PMC10421942/ /pubmed/37567963 http://dx.doi.org/10.1038/s41598-023-40354-8 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Article Solomon, Moses M. Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture |
title | Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture |
title_full | Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture |
title_fullStr | Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture |
title_full_unstemmed | Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture |
title_short | Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture |
title_sort | effective inhibition of t95 steel corrosion in 15 wt% hcl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10421942/ https://www.ncbi.nlm.nih.gov/pubmed/37567963 http://dx.doi.org/10.1038/s41598-023-40354-8 |
work_keys_str_mv | AT solomonmosesm effectiveinhibitionoft95steelcorrosionin15wthclsolutionbyaspartamepotassiumiodideandsodiumdodecylsulphatemixture |