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Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture

Sustainable development goal 12 advocates the production and consumption of green and sustainable commodities. As such, pressure is mounting on the oil and gas industries for a paradigm shift. This work explores the potential of aspartame (a derivative of aspartic acid and phenylalanine) based formu...

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Autor principal: Solomon, Moses M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10421942/
https://www.ncbi.nlm.nih.gov/pubmed/37567963
http://dx.doi.org/10.1038/s41598-023-40354-8
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author Solomon, Moses M.
author_facet Solomon, Moses M.
author_sort Solomon, Moses M.
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description Sustainable development goal 12 advocates the production and consumption of green and sustainable commodities. As such, pressure is mounting on the oil and gas industries for a paradigm shift. This work explores the potential of aspartame (a derivative of aspartic acid and phenylalanine) based formulation as a green inhibitor. The inhibiting effect of aspartame alone and in combination with potassium iodide (KI) or sodium dodecyl sulphate (SDS) or both on T95 steel in 15 wt% HCl solution at 60–90 °C is investigated using weight loss, electrochemical, and surface analysis techniques. The results show severe metal corrosion especially at 90 °C with a corrosion rate (v) of 186.37 mm/y. Aspartame inhibits corrosion and its inhibition efficiency (η) increases with an increase in temperature. At 6.80 mM, η of 86% is obtained at 90 °C. The addition of SDS to aspartame produces an antagonistic effect. A KI-aspartame mixture produces an antagonistic effect at 60 °C and 70 °C but a synergistic effect at 80 °C and 90 °C. There is a strong synergy when aspartame (6.80 mM), KI (1 mM), and SDS (1 mM) are mixed especially at higher temperatures. The mixture reduces v from 186.37 to 14.35 mm/y, protecting the metal surface by 92% at 90 °C. The mixture can be considered an acidizing corrosion inhibitor.
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spelling pubmed-104219422023-08-13 Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture Solomon, Moses M. Sci Rep Article Sustainable development goal 12 advocates the production and consumption of green and sustainable commodities. As such, pressure is mounting on the oil and gas industries for a paradigm shift. This work explores the potential of aspartame (a derivative of aspartic acid and phenylalanine) based formulation as a green inhibitor. The inhibiting effect of aspartame alone and in combination with potassium iodide (KI) or sodium dodecyl sulphate (SDS) or both on T95 steel in 15 wt% HCl solution at 60–90 °C is investigated using weight loss, electrochemical, and surface analysis techniques. The results show severe metal corrosion especially at 90 °C with a corrosion rate (v) of 186.37 mm/y. Aspartame inhibits corrosion and its inhibition efficiency (η) increases with an increase in temperature. At 6.80 mM, η of 86% is obtained at 90 °C. The addition of SDS to aspartame produces an antagonistic effect. A KI-aspartame mixture produces an antagonistic effect at 60 °C and 70 °C but a synergistic effect at 80 °C and 90 °C. There is a strong synergy when aspartame (6.80 mM), KI (1 mM), and SDS (1 mM) are mixed especially at higher temperatures. The mixture reduces v from 186.37 to 14.35 mm/y, protecting the metal surface by 92% at 90 °C. The mixture can be considered an acidizing corrosion inhibitor. Nature Publishing Group UK 2023-08-11 /pmc/articles/PMC10421942/ /pubmed/37567963 http://dx.doi.org/10.1038/s41598-023-40354-8 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Solomon, Moses M.
Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture
title Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture
title_full Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture
title_fullStr Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture
title_full_unstemmed Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture
title_short Effective inhibition of T95 steel corrosion in 15 wt% HCl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture
title_sort effective inhibition of t95 steel corrosion in 15 wt% hcl solution by aspartame, potassium iodide, and sodium dodecyl sulphate mixture
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10421942/
https://www.ncbi.nlm.nih.gov/pubmed/37567963
http://dx.doi.org/10.1038/s41598-023-40354-8
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