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Exploiting reduced-symmetry ligands with pyridyl and imidazole donors to construct a second-generation stimuli-responsive heterobimetallic [PdPtL(4)](4+) cage
A new sequential metalation strategy that enables the assembly of a new more robust reduced symmetry heterobimetallic [PdPtL(4)](4+) cage C is reported. By exploiting a low-symmetry ditopic ligand (L) that features imidazole and pyridine donor units we were able to selectively form a [Pt(L)(4)](2+)...
Autores principales: | Pearcy, Aston C., Lisboa, Lynn S., Preston, Dan, Page, Nick B., Lawrence, Tristan, Wright, L. James, Hartinger, Christian G., Crowley, James D. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10430685/ https://www.ncbi.nlm.nih.gov/pubmed/37592996 http://dx.doi.org/10.1039/d3sc01354e |
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