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Salt mixtures in stone weathering

Salt related weathering of stones has been attributed to pressures exerted by repeated cycles of crystallization within pores. Relative Humidity (RH) is a key driver for dissolution and crystallization processes. Despite the prevalence of salt mixtures in natural environments, most experimental work...

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Autores principales: Godts, Sebastiaan, Orr, Scott Allan, Steiger, Michael, Stahlbuhk, Amelie, De Kock, Tim, Desarnaud, Julie, De Clercq, Hilde, Cnudde, Veerle
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10432528/
https://www.ncbi.nlm.nih.gov/pubmed/37587170
http://dx.doi.org/10.1038/s41598-023-40590-y
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author Godts, Sebastiaan
Orr, Scott Allan
Steiger, Michael
Stahlbuhk, Amelie
De Kock, Tim
Desarnaud, Julie
De Clercq, Hilde
Cnudde, Veerle
author_facet Godts, Sebastiaan
Orr, Scott Allan
Steiger, Michael
Stahlbuhk, Amelie
De Kock, Tim
Desarnaud, Julie
De Clercq, Hilde
Cnudde, Veerle
author_sort Godts, Sebastiaan
collection PubMed
description Salt related weathering of stones has been attributed to pressures exerted by repeated cycles of crystallization within pores. Relative Humidity (RH) is a key driver for dissolution and crystallization processes. Despite the prevalence of salt mixtures in natural environments, most experimental work has focused on single salts. Thus, the identification of salt mixture composition and their behavior is necessary to understand weathering. Thermodynamic calculations are used to analyze several thousand realistic salt mixtures found in weathered stone. We identify two common mixture types and their behavior. From at least 85 salt species theoretically present, 14 common salts are identified that occur most frequently and their critical RH points are discussed. These findings have wide-reaching implications for understanding salt weathering processes and informing the design of experimental stone weathering research.
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spelling pubmed-104325282023-08-18 Salt mixtures in stone weathering Godts, Sebastiaan Orr, Scott Allan Steiger, Michael Stahlbuhk, Amelie De Kock, Tim Desarnaud, Julie De Clercq, Hilde Cnudde, Veerle Sci Rep Article Salt related weathering of stones has been attributed to pressures exerted by repeated cycles of crystallization within pores. Relative Humidity (RH) is a key driver for dissolution and crystallization processes. Despite the prevalence of salt mixtures in natural environments, most experimental work has focused on single salts. Thus, the identification of salt mixture composition and their behavior is necessary to understand weathering. Thermodynamic calculations are used to analyze several thousand realistic salt mixtures found in weathered stone. We identify two common mixture types and their behavior. From at least 85 salt species theoretically present, 14 common salts are identified that occur most frequently and their critical RH points are discussed. These findings have wide-reaching implications for understanding salt weathering processes and informing the design of experimental stone weathering research. Nature Publishing Group UK 2023-08-16 /pmc/articles/PMC10432528/ /pubmed/37587170 http://dx.doi.org/10.1038/s41598-023-40590-y Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Godts, Sebastiaan
Orr, Scott Allan
Steiger, Michael
Stahlbuhk, Amelie
De Kock, Tim
Desarnaud, Julie
De Clercq, Hilde
Cnudde, Veerle
Salt mixtures in stone weathering
title Salt mixtures in stone weathering
title_full Salt mixtures in stone weathering
title_fullStr Salt mixtures in stone weathering
title_full_unstemmed Salt mixtures in stone weathering
title_short Salt mixtures in stone weathering
title_sort salt mixtures in stone weathering
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10432528/
https://www.ncbi.nlm.nih.gov/pubmed/37587170
http://dx.doi.org/10.1038/s41598-023-40590-y
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