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Analytical Model for Pulsed-Laser Induced Mode-Mismatched Dual-Beam Thermal Lens Spectroscopy in Liquids

[Image: see text] Analytical models are very important to understand physical, chemical, and biological phenomena. In many cases, obtaining an analytical model is a complex, even an impossible task. In this work, an analytical model for thermal lens spectroscopy has been developed. The model conside...

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Autores principales: Isidro-Ojeda, Michel A., Alvarado-Gil, Juan J., Capeloto, Otávio A., Zambrano-Arjona, Miguel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10433338/
https://www.ncbi.nlm.nih.gov/pubmed/37599977
http://dx.doi.org/10.1021/acsomega.3c03297
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author Isidro-Ojeda, Michel A.
Alvarado-Gil, Juan J.
Capeloto, Otávio A.
Zambrano-Arjona, Miguel A.
author_facet Isidro-Ojeda, Michel A.
Alvarado-Gil, Juan J.
Capeloto, Otávio A.
Zambrano-Arjona, Miguel A.
author_sort Isidro-Ojeda, Michel A.
collection PubMed
description [Image: see text] Analytical models are very important to understand physical, chemical, and biological phenomena. In many cases, obtaining an analytical model is a complex, even an impossible task. In this work, an analytical model for thermal lens spectroscopy has been developed. The model considers light absorbing liquids, a laser pulsed beam as the heat source, timescale thermal regime, and small phase change produced by heating. A simplification for low-absorption samples is obtained. A complete theoretical study of their utilization is shown. Measurements of the thermal diffusivity of water–ethanol sample mixtures in the liquid phase are analyzed. These values for pure substances are in good agreement with those reported in the literature. Our methodology could be very useful in the analysis of the optical and thermal properties of liquids.
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spelling pubmed-104333382023-08-18 Analytical Model for Pulsed-Laser Induced Mode-Mismatched Dual-Beam Thermal Lens Spectroscopy in Liquids Isidro-Ojeda, Michel A. Alvarado-Gil, Juan J. Capeloto, Otávio A. Zambrano-Arjona, Miguel A. ACS Omega [Image: see text] Analytical models are very important to understand physical, chemical, and biological phenomena. In many cases, obtaining an analytical model is a complex, even an impossible task. In this work, an analytical model for thermal lens spectroscopy has been developed. The model considers light absorbing liquids, a laser pulsed beam as the heat source, timescale thermal regime, and small phase change produced by heating. A simplification for low-absorption samples is obtained. A complete theoretical study of their utilization is shown. Measurements of the thermal diffusivity of water–ethanol sample mixtures in the liquid phase are analyzed. These values for pure substances are in good agreement with those reported in the literature. Our methodology could be very useful in the analysis of the optical and thermal properties of liquids. American Chemical Society 2023-08-02 /pmc/articles/PMC10433338/ /pubmed/37599977 http://dx.doi.org/10.1021/acsomega.3c03297 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Isidro-Ojeda, Michel A.
Alvarado-Gil, Juan J.
Capeloto, Otávio A.
Zambrano-Arjona, Miguel A.
Analytical Model for Pulsed-Laser Induced Mode-Mismatched Dual-Beam Thermal Lens Spectroscopy in Liquids
title Analytical Model for Pulsed-Laser Induced Mode-Mismatched Dual-Beam Thermal Lens Spectroscopy in Liquids
title_full Analytical Model for Pulsed-Laser Induced Mode-Mismatched Dual-Beam Thermal Lens Spectroscopy in Liquids
title_fullStr Analytical Model for Pulsed-Laser Induced Mode-Mismatched Dual-Beam Thermal Lens Spectroscopy in Liquids
title_full_unstemmed Analytical Model for Pulsed-Laser Induced Mode-Mismatched Dual-Beam Thermal Lens Spectroscopy in Liquids
title_short Analytical Model for Pulsed-Laser Induced Mode-Mismatched Dual-Beam Thermal Lens Spectroscopy in Liquids
title_sort analytical model for pulsed-laser induced mode-mismatched dual-beam thermal lens spectroscopy in liquids
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10433338/
https://www.ncbi.nlm.nih.gov/pubmed/37599977
http://dx.doi.org/10.1021/acsomega.3c03297
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