Molecular rearrangement of bicyclic peroxy radicals is a key route to aerosol from aromatics

The oxidation of aromatics contributes significantly to the formation of atmospheric aerosol. Using toluene as an example, we demonstrate the existence of a molecular rearrangement channel in the oxidation mechanism. Based on both flow reactor experiments and quantum chemical calculations, we show t...

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Detalles Bibliográficos
Autores principales: Iyer, Siddharth, Kumar, Avinash, Savolainen, Anni, Barua, Shawon, Daub, Christopher, Pichelstorfer, Lukas, Roldin, Pontus, Garmash, Olga, Seal, Prasenjit, Kurtén, Theo, Rissanen, Matti
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10435581/
https://www.ncbi.nlm.nih.gov/pubmed/37591852
http://dx.doi.org/10.1038/s41467-023-40675-2

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10435581/
https://www.ncbi.nlm.nih.gov/pubmed/37591852
http://dx.doi.org/10.1038/s41467-023-40675-2

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