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Molecular rearrangement of bicyclic peroxy radicals is a key route to aerosol from aromatics
The oxidation of aromatics contributes significantly to the formation of atmospheric aerosol. Using toluene as an example, we demonstrate the existence of a molecular rearrangement channel in the oxidation mechanism. Based on both flow reactor experiments and quantum chemical calculations, we show t...
| Autores principales: | , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10435581/ https://www.ncbi.nlm.nih.gov/pubmed/37591852 http://dx.doi.org/10.1038/s41467-023-40675-2 |