Cargando…
Kinetics and Mechanism of Azole n−π*-Catalyzed Amine Acylation
[Image: see text] Azole anions are highly competent in the activation of weak acyl donors, but, unlike neutral (aprotic) Lewis bases, are not yet widely applied as acylation catalysts. Using a combination of in situ and stopped-flow (1)H/(19)F NMR spectroscopy, kinetics, isotopic labeling, (1)H DOSY...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10436283/ https://www.ncbi.nlm.nih.gov/pubmed/37526380 http://dx.doi.org/10.1021/jacs.3c06258 |